We investigated the use of waste glass fiber-reinforced plastic (GFRP) to remove dye from industrial wastewater. The dye adsorbent material, based on GFRP/clay ceramics, was produced by mixing crushed GFRP with clay and firing the resulting mixture. Several types of ceramics were produced by adjusting the mixing ratio of clay, crushed 40% GF/GFRP, and firing atmosphere. Adsorption tests with methylene blue (MB) dye were performed by mixing the ceramics into an MB solution while controlling the stirring speed and measuring the decrease in MB dye concentration over time. These results showed that GFRP/clay ceramics reductively fired at 1073 K had a higher MB dye adsorption ability than that of the clay ceramic. The MB dye absorptivity of the reductively fired ceramics increased as we increased the mixing ratio of GFRP. We attribute this result to the high plastic carbide content in the ceramic, which has excellent dye absorbability. Furthermore, these particles had a comparatively high specific surface area and porosity.

The effective reuse of waste glass fiber-reinforced plastic (GFRP) is desired. We previously produced porous ceramics by firing mixtures of crushed GFRP and clay in a reducing atmosphere and demonstrated their applicability as adsorbents for the removal of basic dyes from dyeing wastewater. However, the primary influencing factors and the dye adsorption mechanism have not been fully elucidated, and the adsorption of acidic and direct dyes has not been clarified. In this study, adsorption tests were conducted, and the effects of the firing atmosphere, specific surface area, type of dye, and individual components were comprehensively investigated. The results showed that reductively fired ceramics containing plastic carbide residue adsorbed basic dye very well but did not adsorb acidic dye well. The clay structure was the primary factor for the dye adsorption rather than the GFRP carbide. The mechanism for the basic dye adsorption appears to have been an increase in specific surface area due to the plastic carbide residue in the ceramic structure, which increased the ion exchange between the clay minerals and the dye. By adjusting the pH of the aqueous solution, the GFRP/clay ceramic also adsorbed considerable amounts of direct dye, so the mechanism was determined to be ion exchange with the calcium component of the glass fibers.

“Akahoya” is a volcanic soil classified as a special soil deposited in Kyushu, Japan. Many of its properties are not yet clearly understood. We found that Akahoya had the potential to adsorb bacteria in cattle feces, which prompted us to investigate its material properties and perform experiments to comprehensively evaluate its adsorption performance for various fine particles such as acidic and basic dyes, NO_x/SO_x gas, and phosphoric acid ions, in addition to bacteria. Akahoya had a very high specific surface area owing to the large number of nanometer-sized pores in its structure; it exhibited a high adsorption capacity for both NO₂ and SO₂. Regarding the zeta potential of Akahoya, the point of zero charge was approximately pH 7.0. The surface potential had a significant effect on the adsorption of acidic and basic dyes. Akahoya had a very high cation exchange capacity when the sample surface was negatively charged and a high anion exchange capacity when the sample surface was positively charged. Akahoya also exhibited a relatively high adsorption capacity for phosphoric acid because of its high level of Al₂O₃, and the immersion liquid had a very high Al ion concentration. Finally, filtration tests were performed on Escherichia coli suspension using a column filled with Akahoya or another volcanic soil sample. The results confirmed that the Escherichia coli adhered on the Akahoya sample. The results of the Escherichia coli release test, after the filtration test, suggested that this adhesion to Akahoya could be phosphorus-mediated.

To reuse waste glass fiber-reinforced plastics (GFRPs), porous ceramics (i.e., GFRP/clay ceramics) were produced by mixing crushed GFRP with clay followed by firing the resulting mixture under different conditions. The possibility of using ceramics fired under a reducing atmosphere as adsorbent materials to remove NO_x and SO_x from combustion gases of fossil fuels was investigated because of the high porosity, specific surface area, and contents of glass fibers and plastic carbides of the ceramics. NO₂ and SO₂ adsorption tests were conducted on several types of GFRP/clay ceramic samples, and the gas concentration reduction rates were compared to those of a clay ceramic and a volcanic pumice with high NO₂ adsorption. In addition, to clarify the primary factor affecting gas adsorption, adsorption tests were conducted on the glass fibers in the GFRP and GFRP carbides. The reductively fired GFRP/clay ceramics exhibited high adsorption performance for both NO₂ and SO₂. The primary factor affecting the NO₂ adsorption of the ceramics was the plastic carbide content in the clay structure, while that affecting the SO₂ adsorption of the ceramics was the glass fiber content.

This study addresses the problem of pumice deposits in the southern Kyushu region, which can cause landslides during heavy rainfall. To reduce this hazard, it is important to expand pumice applications and promote its use before disaster events occur. Among construction materials, this study explores the possibility of using pumice as a concrete aggregate, considering the global shortage of natural aggregates. Because of the low strength and difficulty of use, pumice must be fired to improve its properties. In our experiment, it was fired at 1000 or 1100 °C, and the performance of the resulting concretes was compared. Concrete incorporating pumice fired at 1100 °C achieved a maximum compressive strength of 54.6 N/mm² with an increase in the amount of cement, whereas concrete with pumice fired at 1000 °C remained within the 20–24 N/mm² range even when the amount of cement was increased. This difference arises because pumice has a lower strength than the cement paste, leading to material failure. Furthermore, freeze–thaw tests showed that concrete made with pumice fired at 1100 °C was resistant to frost damage. These results suggest that pumice fired at 1100 °C has an excellent potential as a sustainable building material.

Glass cullet (GC) generated from the disposal of photovoltaic (PV) panels are typically landfilled, and effective GC utilization methods must be established for PV generation. In this study, alkali-activated material (AAM) mortars were prepared from the paste of fine blast-furnace slag powder, fly ash, and sodium orthosilicate (SO) and mixed with crushed sand and GC to investigate the potential use of GC as a fine aggregate in AAM. The replacement of crushed sand with GC did not considerably affect the flowability of the mortar, whereas the compressive strength decreased with the increasing GC replacement rates. Although expansion due to the alkali–silica reaction (ASR) was observed in mortars wherein GC replaced crushed sand, the expansion can be controlled by reducing the amount of mixed SO, autoclaving the GC, performing preleaching to remove the Si that causes the ASR, and replacing the blast-furnace slag with fly ash. By enforcing measures against the expansion, the possibility of using GC as fine aggregate is enhanced considerably, thus increasing the feasibility of continuous PV production.