Time and place of electron exit: Until about a decade ago, laser-induced ionization was considered instantaneous. Since then, applications of attosecond laser pulses have shown multiple subtle and complex factors that influence the precise timing of electron ejection from atoms and surfaces. Vos et al. measured the corresponding attosecond dynamics of dissociative photoionization in a diatomic molecule, carbon monoxide. By imaging the charged fragments, the timing could be correlated with the specific spatial portion of the molecule from which the electron wave packet emerged. Science , this issue p. 1326

Recent progress in the generation of ultra-short laser pulses has enabled the measurement of photoionization time delays with attosecond precision. For single photoemission time delays the most common techniques are based on attosecond streaking and the reconstruction of attosecond beating by interference of two-photon transitions (RABBITT). These are pump-probe techniques employing an extreme-ultraviolet (XUV) single attosecond pump pulse for streaking or an attosecond pump pulse train for RABBITT, and a phase-locked infrared (IR) probe pulse. These techniques can only extract relative timing information between electrons originating from different initial states within the same atom or different atoms. Here we address the question whether the two techniques give identical timing information. We present a complete study, supported by both experiments and simulations, comparing these two techniques for the measurement of the photoemission time delay difference between valence electrons emitted from the Ne 2p and Ar 3p ground states. We highlight not only the differences and similarities between the two techniques, but also critically investigate the reliability of the methods used to extract the timing information.

Ultra low energy ion implantation is a promising technique for the wafer-scale fabrication of Silver nanoparticle planar arrays embedded in thermal silica on silicon substrate. The stability versus time of these nanoparticles is studied at ambient conditions on a time scale of months. The plasmonic signature of Ag NPs vanishes several months after implantation for as-implanted samples, while samples annealed at intermediate temperature under N₂ remain stable. XPS and HREM analysis evidence the presence of Silver oxide nanoparticles on aged samples and pure Silver nanoparticles on the annealed ones. This thermal treatment does not modify the size-distribution or position of the particles but is very efficient in stabilizing the metallic particles and to prevent any form of oxidation.

Liquid crystals are superior optical materials for large area displays, but it is considered that their collective and slow-millisecond response makes them useless for ultrafast optical applications. In contrast to that, we here demonstrate an ultrafast optical response of a nematic liquid crystal, which is induced by an intense femtosecond optical impulse. We show that the refractive index of the nematic liquid crystal pentyl-cyanobiphenyl can be modulated at a time scale as fast as 500 fs via a coherently excited optical Kerr effect. The change in the refractive index is in the order of 10⁻⁴ at a fluence of 4 mJ/cm² and is strongly polarization dependent. This unprecedented result opens new ways towards ultrafast all-optical modulation in liquid crystal-based devices.