As an effective technology for enhancing oil recovery, low-salinity water flooding requires further investigation into its microscopic displacement mechanisms and the regulatory roles of key ions. Based on microscopic visualization displacement experiments, this study systematically investigated the effects of injected water salinity, key ion types (Na⁺, K⁺, Ca²⁺, Mg²⁺, HCO₃⁻, CO₃²⁻, SO₄²⁻, and OH⁻), and their concentrations on crude oil displacement behavior in both high- and low-permeability zones. Experimental results indicate that no significant correlation exists between displacement efficiency and injected water salinity in high-permeability zones. In low-permeability zones, displacement efficiency increases with decreasing salinity, peaking at 26.5% when injected water salinity reaches 5000 mg/L. The cation displacement efficiency in the formation, from highest to lowest, is Ca²⁺ > K⁺ > Mg²⁺ > Na⁺. The anion displacement efficiency, from highest to lowest, is OH⁻ > SO₄²⁻ > CO₃²⁻ > HCO₃⁻. When the CaCl₂ concentration decreased from 100 wt% to 50 wt%, the displacement effect in the low-permeability zone improved further, indicating that a higher concentration of the divalent cation Ca²⁺ is not necessarily better. In medium-to-high salinity formation water reservoirs, and under conditions where the influence of clay minerals is disregarded, ion type and reservoir permeability are the most significant factors affecting oil recovery efficiency. These findings provide theoretical support for elucidating the micro-dynamic mechanisms of low-salinity water flooding in low-permeability zones and optimizing injection water formulations.

Aiming at the unclear mechanisms of fluid migration in nanopore-throat systems within tight oil reservoirs, this study focuses on the microscopic interactions at the oil–water interface in nanoconfined spaces. Based on molecular dynamics simulation, water-flooding models within nanopores of tight oil reservoirs under varying salinity conditions were constructed. The microscopic flow behaviors of oil and water in the pores were investigated, and the mechanism by which interfacial hydrogen bonding influences displacement efficiency under nanoconfinement was elucidated. The results demonstrate that due to the strong hydrogen bonding interactions between acetic acid and water, it is impossible to establish an effective displacement process or form stable displacement pathways within the pores. The extensive hydrogen-bonding network formed by acetic acid molecules at the oil–water interface severely restricts the transport capacity of water. Salinity exerts a nonlinear regulatory effect on hydrogen bonding. High-salinity (246.5 g/L) waterflooding shortens hydrogen bond lengths, enhances local bonding strength, and restricts the expansion of water channels; low-salinity (21.9 g/L) waterflooding mitigates ionic interference, resulting in the highest diffusion capacity of alkanes. The diffusion coefficient increases by 1.4 times compared to that under high-salinity conditions, leading to the highest degree of crude oil mobility. The research findings provide important guidance for enhanced oil recovery in tight oil reservoirs.