At present, the world is committed to the development of environmentally friendly, sustainable and industrial safety. The effective treatment of industrial solid waste can be applied in the field of industrial safety. It is one of the ways to apply industrial solid waste to industrial safety to modify industrial solid waste and combine active powder to prepare industrial solid waste-based composite powder explosion inhibitors and apply it to underground coal dust explosion. This paper introduces the modification and preparation methods of industrial solid waste, and analyzes the good explosion suppression effect and good economic benefit of industrial solid waste-based composite powder explosion inhibitors on coal dust explosion. In this paper, four kinds of industrial solid wastes (red mud, slag, fly ash and sludge) were modified, and the modified solid waste materials with good carrier characteristics were obtained. Combined with a variety of active powders (NaHCO3, KH2PO4 and Al(OH)3), the industrial solid waste-based composite powder explosion inhibitors were obtained by solvent-crystallization (WCSC) and dry coating by ball milling (DCBM). Those kinds of explosion inhibitors can suppress the explosion of pulverized coal in 40–50% of cases. Compared with the powder explosion inhibitor commonly used in industry, it has a lower production cost and better explosion suppression effect. Those kinds of explosion inhibitors have a good industrial application prospect.
Coal and oil shale are often mined and utilized together, and mixed dust is easily formed in these processes. In order to ensure safe production in these processes, the explosion characteristics of mixed dust were studied. Using a Godbert-Greenwold (G-G) Furnace experimental device, Hartmann tube experimental device, and 20 L explosion vessel, the oil shale and coal mixed dust ignition sensitivity experiment, flame propagation experiment, and explosion characteristics experiment were carried out. The minimum ignition temperature (MIT), minimum ignition energy (MIE), maximum explosion pressure (Pmax), maximum rate of pressure rise ((dp/dt)max), and explosibility index (KSt) parameters and the flame propagation behavior of the mixed dust were analyzed in detail. A scanning electron microscope (SEM) analysis of the coal and oil shale dust before and after the explosion was carried out to study the changes in the microscopic morphology of the dust particles. The results show that due to the oil shale having a high volatile content and low moisture content, in the mixture, the greater the percentage of oil shale, the more likely the dust cloud is to be ignited and the faster the explosion flame is propagated; the greater the percentage of oil shale, the greater the (dP/dt)max and KSt will be and, under a high dust concentration, a greater Pmax will be produced. During explosion, coal dust will experience particle pyrolysis and the gas phase combustion of the volatile matter, followed by solid phase combustion of coal char, whereas oil shale dust will only experience particle pyrolysis and the gas phase combustion of the volatile matter.
In this paper, a method for waste incineration slag is proposed. An incineration acidification alkalization modification was carried out based on the characteristics of the oxides (SiO2, CaO, Al2O3, Fe2O3, and MgO) of waste incineration slag. With modified slag as the carrier and NaHCO3 as the supporter, a slag-based composite powder explosion inhibitor was prepared with the solvent-crystallization wet coating (WCSC), ball milling dry coating (DCBM), and air impact dry coating (DCAI) methods. The advantages and disadvantages of the three methods were compared and analyzed. Explosion suppression experiments on oil shale dust were carried out, and the explosion suppression mechanism was described. The explosion suppression process of the modified slag–NaHCO3 composite powder explosion inhibitor for oil shale dust was found to involve a synergy of physical and chemical inhibition. This explosion suppression mechanism indicates three requirements for the preparation and application of industrial solid waste-based composite powder explosion inhibitors. The feasibility of preparing composite powder explosion inhibitors from waste incinerator slag was discussed from the experimental point of view and its explosion suppression performance on oil shale dust was studied with the intention of providing a new form of resource utilization for waste incinerator slag.
1 February 2020 in IOP Conference Series: Earth and Environmental Science
The occupational health efforts within Y Group are examined after analysis on current occupational health and occupational hazard control among coal mines in and outside China, covering a systematic investigation of dust hazard prevention in B Mine and an analytical research of heat hazard in Z Mine. The paper includes an innovative set of studies on the distributions of coal mine workers subject to different occupational hazards and the types of work among pneumoconiosis victims, the distribution of main heat sources underground and measures against heat hazards, as well as the number of dust-exposed workers per ten thousand tons of raw coal. Our findings will provide useful clues for successful occupational health and occupational hazard control in the coal sector.
A large amount of waste dust will be produced in the process of metal grinding, resulting in a waste of resources and environmental pollution. Therefore, we present a new method of inerting waste aluminum (Al) alloy dust for recycling purposes. Three natural high polymers—starch, pectin, and hydroxypropyl cellulose—were selected to inert waste metal dust in order to prevent the alloy from hydrolyzing and keep the dust pure enough for reuse. The particles of the Al base alloy before and after dust reaction were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier transform infra-red (FTIR), and the relevant reaction mechanism was clarified. The hydrogen evolution test indicated that, across the temperature interval of 313–333 K, 0.75 wt% pectin inerted hydrogen evolution most efficiently (90.125%). XRD analysis indicated that the inerted product is composed of Al monomer and Al3Mg2, with no detectable content of Al hydroxide. The purity of the Al alloy dust was preserved. SEM and FTIR analyses indicated that the -OH, -COOH, and -COOCH3 functional groups in the high polymer participated in the coordination reaction by adsorbing on the surface of the waste Al alloy particles to produce a protective film, which conforms to Langmuir’s adsorption model. Verification of the inerted Al alloy dust in industrial production confirmed the possibility of reusing waste Al alloy dust. This study provides a simple and effective method for recycling waste Al alloy dust.
About Me
Dr. of Northeastern University, devoted to the research of industrial gas explosion protection.
Dr. of Northeastern University, devoted to the research of industrial gas explosion protection.