Graphitic carbon nitride (g-C₃N₄) has proved to be a promising heterogeneous photocatalyst in the visible range. It can be used, among others, for the oxidative conversion of environmentally harmful nitrophenols occurring in wastewater. However, its photocatalytic activity needs to be enhanced, which can be achieved by modification with various dopants. In our work, copper-modified g-C₃N₄ was prepared by ultrasonic impregnation of the pristine g-C₃N₄ synthesized from thiourea. The morphology, microstructure, and optical properties of the photocatalysts were characterized by XRD, FT-IR, DRS, SEM, XPS, and TEM. DRS analysis indicated a slight change in both the CB and the VB energies of Cu/g-C₃N₄ compared to those of g-C₃N₄. The efficiency of the photocatalysts prepared was tested by the degradation of nitrophenols. Copper modification caused a sevenfold increase in the rate of 4-nitrophenol degradation in the presence of H₂O₂ at pH = 3. This dramatic enhancement can be attributed to the synergistic effect of copper and H₂O₂ in this photocatalytic system. A minor Fenton reaction role was also detected. The reusability of the Cu/g-C₃N₄ catalyst was demonstrated through five cycles. Copper-modified g-C₃N₄ with H₂O₂ proved to be applicable for efficient visible-light-driven photocatalytic oxidative degradation of nitrophenols.

Catalysts for visible-light-driven oxidative cleaning processes and antibacterial applications (also in the dark) were developed. In order to extend the photoactivity of titanium dioxide into the visible region, nitrogen-doped TiO₂ catalysts with hollow and non-hollow structures were synthesized by co-precipitation (NT-A) and sol–gel (NT-U) methods, respectively. To increase their photocatalytic and antibacterial efficiencies, various amounts of silver were successfully loaded on the surfaces of these catalysts by using a facile photo-deposition technique. Their physical and chemical properties were evaluated by using scanning electron microscopy (SEM), transmission electron microscopy–energy dispersive X-ray spectroscopy (TEM–EDS), Brunauer–Emmett–Teller (BET) surface area, X-ray diffraction (XRD), and diffuse reflectance spectra (DRS). The photocatalytic performances of the synthesized catalysts were examined in coumarin and 1,4-hydroquinone solutions. The results showed that the hollow structure of NT-A played an important role in obtaining high specific surface area and appreciable photoactivity. In addition, Ag-loading on the surface of non-hollow structured NT-U could double the photocatalytic performance with an optimum Ag concentration of 10⁻⁶ mol g⁻¹, while a slight but monotonous decrease was caused in this respect for the hollow surface of NTA upon increasing Ag concentration. Comparing the catalysts with different structures regarding the photocatalytic performance, silverized non-hollow NT-U proved competitive with the hollow NT-A catalyst without Ag-loading for efficient visible-light-driven photocatalytic oxidative degradations. The former one, due to the silver nanoparticles on the catalyst surface, displayed an appreciable antibacterial activity, which was comparable to that of a reference material practically applied for disinfection in polymer coatings.

It is well known that surfactants increase the solubility of hydrophobic organic compounds and cause adverse environmental effects. The removal of these compounds from the contaminated soil or ground-water is particularly difficult due to their water soluble feature. In this work, an ultra-high performance hydrophilic interaction liquid chromatographic method was developed for the separation of oligomers of Triton X-100 octylphenol-polyethoxylate non-ionic surfactant. Liquid chromatography-mass spectrometry (LC-MS) was used to identify the Triton X-100 compounds. There was a 44 mass unit difference between two adjacent peaks that is the molar mass of one ethylene oxide group (–CH ${}_2$ CH ${}_2$ O–). A quadratic retention model was applied for the estimation of retention of the examined non-ionic surfactant and the optimization of gradient elution conditions. The optimized method was suitable for the baseline separation of 28 Triton X-100 oligomers in five minutes.

Graphitic carbon nitride (g-C₃N₄) proved to be a promising semiconductor for the photocatalytic degradation of various organic pollutants. However, its efficacy is limited by a fast electron hole recombination, a restricted quantity of active sites, and a modest absorption in the visible range. To overcome these limitations, g-C₃N₄-Bi₂S₃ and g-C₃N₄-ZnS composites were effectively produced utilizing a starch-assisted technique. The findings from FT-IR, XRD, EDX, XPS, BET, SEM, and TEM demonstrated that the enhanced photocatalytic activity of g-C₃N₄-Bi₂S₃ and g-C₃N₄-ZnS composites was primarily due to their improved photocarrier separation and transfer rates. The photocatalyst facilitated the aerobic photocatalytic degradation of colorless contaminants such as coumarin and para-nitrophenol (4-NP). For the decomposition of 4-NP, g-C₃N₄-Bi₂S₃ exhibited a maximum efficiency of 90.86% in UV light and 16.78% in visible light, with rate constants of 0.29 h⁻¹ and 0.016 h⁻¹, respectively. In contrast, g-C₃N₄-ZnS demonstrated a maximum efficiency of 100% in UV light and 15.1% in visible light, with rate constants of 0.57 h⁻¹ and 0.018 h⁻¹, respectively. The bioinspired synthesis combined with the modification with metal sulfides proved to considerably enhance the photocatalytic activity of g-C₃N₄, increasing its potential for practical applicability in environmentally friendly water treatment systems for the efficient removal of recalcitrant organic contaminants.

The heterogeneous photo-Fenton type system has huge fame in the field of wastewater treatment due to its reusability and appreciable photoactivity within a wide pH range. This research investigates the synthesis and characterization of iron(II) doped copper ferrite (Cu^II_(x)Fe^II_(1-x)Fe^III₂O₄ nanoparticles (NPs) and their photocatalytic applications for the degradation of methylene blue (MB) as a model dye. The NPs were prepared via simple co-precipitation technique and calcination. The NPs were characterized by using Raman spectroscopy, X-ray diffractometry (XRD), scanning electron microscopy (SEM), and diffuse reflectance spectroscopy (DRS). SEM reveals the structural change from the spherical-like particles into needle-like fine particles as the consequence of the increasing ratio of copper(II) in the ferrites, accompanied by the decrease of the optical band-gap energies from 2.02 to 1.25 eV. The three major determinants of heterogeneous photo-Fenton system, namely NPs concentration, hydrogen peroxide concentration and pH, on the photocatalytic degradation of MB were studied. The reusability of NPs was found to be continuously increasing during 4 cycles. It was concluded that iron(II) doped copper ferrites, due to their favorable band-gap energies and peculiar structures, exhibit a strong potential for photocatalytic-degradation of dyes, for example, MB.