By applying 2205 duplex stainless steel powders to repair and improve carbon steel, multi-pass laser-cladding tests were conducted on Q235 carbon steel surfaces with different laser powers in the range of 1.9~2.5 kW in order to evaluate the performance of the laser-cladding layers. The phase composition, macro- and microstructure, electrochemical corrosion resistance, friction, and wear resistance of the laser-cladding layers were investigated. Macroscopic observation identified no obvious cracks. The phases that made up the multi-pass laser-cladding layers were γ-Fe and α-Fe. Owing to the optimal laser power at 2.3 kW, a large number of equiaxed crystals and a small number of cellular crystals made up the microstructure of the prepared laser-cladding layer, which contributed to its good corrosion resistance. The wear resistance of the multi-pass laser-cladding layer and the carbon steel was also studied. A combined action of adhesive wear and abrasive wear, accompanied by oxidative wear, was determined through observation of pits and furrows on the friction surface of the multi-pass laser-cladding layer, while a typical mechanism of abrasive wear was confirmed by checking the friction surface of the carbon steel.

Organic/inorganic hybrid perovskite materials, such as CH₃NH₃PbX₃ (X = I, Br), have attracted the attention of the scientific community due to their excellent properties such as a widely tunable bandgap, high optical absorption coefficient, excellent power conversion efficiency, etc. The exposure of perovskite solar cells and photovoltaic devices to heat can significantly degrade their performance. Therefore, elucidating their temperature-dependent optical properties is essential for performance optimization of perovskite solar cells. We synthesized CH₃NH₃PbBr₃ (MAPbBr₃) single crystals through the polymer-controlled nucleation route and investigated the optical properties and molecular structure evolution of them with temperature. Through temperature evolution photoluminescence (PL) spectroscopy, we found that the fluorescence intensity was greatly affected by increasing the temperature, with an asymmetric PL profile suggesting that more captured excitons undergo radiative complexation. The optical photographs showed that the color of MAPbBr₃ single crystals faded. Raman spectroscopy revealed that during the heating process, the structure of MAPbBr₃ was still preserved at 90 °C since all of the Raman bands were very clear. When the temperature increased to 120 °C, the Raman bands of the internal modes became very weak. On further heating, the inorganic framework on sample’s surface started to disintegrate above 210 °C. During the heating process, the PL spectra exhibited significant changes in spectral intensity, peak position and Full Width Half Maximum (FWHM). The PL spectral intensity decreased abruptly with increasing temperature. The peak position was blue shifted with increasing temperature, and the peak shape showed an obvious asymmetry. The FMWH of the PL spectra was gradually broadened with the increase in the temperature, and there was a sharp increase from 270 °C to 300 °C. These variations in the PL spectra with temperature indicate that the optical properties of MAPbBr₃ are greatly affected by temperature, which in turn affects the application of MAPbBr₃ in fields such as optical devices. These results may be instructive for the application of MAPbBr₃.