Semiconductor-sensitized TiO₂ solar cells employing CdSe as a light absorber demonstrate superior photovoltaic performance to the best-performing cascaded CdS/CdSe cells with practically identical optical density in the study. A careful comparison between CdSe and CdS/CdSe sensitized cells reveals that while CdS can greatly promote the subsequent growth of CdSe in the cascade electrodes and hence light harvesting, the presence of a CdS buffer layer impedes the injection of electrons from CdSe to TiO₂ and accelerates charge recombination at the TiO₂/sensitizer interface. As a result, better performance was achieved with CdSe-sensitized solar cells when light absorption is identical to that of CdS/CdSe cells, making the CdS buffer layer redundant. CdSe-sensitized TiO₂ solar cells incorporating light scattering layers and an aqueous polysulfide electrolyte yielded an unprecedented power conversion efficiency of up to 5.21% under simulated AM 1.5, 100 mW cm⁻² illumination.

Visible-light-responsive photocatalytic materials have a multitude of important applications, ranging from energy conversion and storage to industrial waste treatment. Molybdenum disulfide (MoS₂) and its variants exhibit high photocatalytic activity under irradiation by visible light as well as good stability and recyclability, which are desirable for all photocatalytic applications. MoS₂-based materials have been widely applied in various fields such as wastewater treatment, environmental remediation, and organic transformation reactions because of their excellent physicochemical properties. The present review focuses on the fundamental properties of MoS₂, recent developments and remaining challenges, and key strategies for tackling issues related to the utilization of MoS₂ in photocatalysis. The application of MoS₂-based materials in visible-light-induced catalytic reactions for the treatment of diverse kinds of pollutants including industrial, environmental, pharmaceutical, and agricultural waste are also critically discussed. The review concludes by highlighting the prospects of MoS₂ for use in various established and emerging areas of photocatalysis.