Conductive polymer, polypyrrole (PPy), was synthesized by chemical oxidative polymerization technique for a period of four hours at room temperature using pyrrole monomer (mPPy) in aqueous solution. Different oxidants such as ferric chloride (FeCl₃) and ammonium persulphate (N₂H₈S₂O₈) and surfactant sodium dodecyl sulphate (C₁₂H₂₅NaO₄S) were used. The produced PPy samples were characterized by using different techniques such as the electrical resistivity by four probe technique, thermogravimetry analysis (TGA), differential scanning calorimetry (DSC), Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), and scanning electron microscopy (SEM). The performance of the oxidants has been investigated and compared. It was found that both oxidants, FeCl₃ and N₂H₈S₂O₈, have decreased electrical resistivity as a function of temperature, which means increased conductivity. However, FeCl₃ has achieved better performance than N₂H₈S₂O₈, where it has achieved a lower resistivity of about 60 ohms at room temperature, which indicates higher conductivity of PPy samples with FeCl₃ as an oxidant. Similarly, further investigation of FeCl₃ oxidant has been conducted by varying its concentration, and its influence on the final properties was reported. It has been observed that the morphology of PPy samples has a significant influence on the conductivity. It was found that 0.1 M and 0.05 M concentrations of FeCl₃ oxidant and monomer, respectively, have achieved better thermal stability, which is FeCl₃/mPPy ratio of 2 as an optimum value. FTIR and XRD results confirmed the structural formation of polypyrrole from pyrrole monomer during the synthesizing process.

In this research work, graphene nanoplatelets (GNP) were selected as alternative reinforcing nanofillers to enhance the properties of polypropylene (PP) using different compatibilizers called polypropylene grafted maleic anhydride (PP-g-MA) and ethylene-octene elastomer grafted maleic anhydride (POE-g-MA). A twin screw extruder was used to compound PP, GNP, and either the PP-g-MA or POE-g-MA compatibilizer. The effect of GNP loading on mechanical and thermal properties of neat PP was investigated. Furthermore, the influence and performance of different compatibilizers on the final properties, such as mechanical and thermal, were discussed and reported. Tensile, flexural, impact, melting temperature, crystallization temperature, and thermal stability were evaluated by using a universal testing system, differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA). For mechanical properties, it was found that increasing GNP content from 1 wt.% to 5 wt.% increased tensile strength of the neat PP up to 4 MPa. The influence of compatibilizers on the mechanical properties had been discussed and reported. For instance, the addition of PP-g-MA compatibilizer improved tensile strength of neat PP with GNP loading. However, the addition of compatibilizer POE-g-MA slightly decreased the tensile strength of neat PP. A similar trend of behavior was observed for flexural strength. For thermal properties, it was found that both GNP loading and compatibilizers have no significant influence on both crystallization and melting temperature of neat PP. For thermal stability, however, it was found that increasing the GNP loading had a significant influence on improving the thermal behavior of neat PP. Furthermore, the addition of compatibilizers into the PP/GNP nanocomposite had slightly improved the thermal stability of neat PP.

The methodology to study an eco-friendly and non-toxic, Schizophyllan, biopolymer for enhanced oil recovery (EOR) polymer flooding is described. The methodology is divided into two parts; the first part estimates the molar concentration of the biopolymer, which is needed to prepare the biopolymer solution with optimal viscosity. This is required to improve the sweep efficiency for the selected reservoir in Kuwait. The second part of this generalized methodology evaluates the biopolymer solution capability to resist degradation and maintain its essential properties with the selected reservoir conditions. The evaluation process includes thermal and mechanical assessment. Furthermore, to study the biopolymer solution behavior in both selected reservoir and extreme conditions, the biopolymer solution samples were prepared using 180 g/L and 309 g/L brine. It was found that the prepared biopolymer solution demonstrated great capability in maintaining its properties; and therefore, can be introduced as a strong candidate for EOR polymer flooding with high salinity brines.