HfO2 thin films were prepared using radio frequency (RF) ion source-assisted deposition, and the effects of auxiliary ion energy on the microstructure, optical properties, and residual stress of the films were systematically studied. The experimental results showed that when the auxiliary ion energy increased, the extinction coefficient, compressive stress, and optical band gap were gradually increased. These changes were attributed to increased grain boundary defects, crystal structure disorder, and grain size decrease due to high-energy ion bombardment. The HfO2 films deposited at a lower ion energy (600 V) exhibited higher surface quality (RMS = 0.78 nm), better optical properties (k = 10⁻5), and lower residual stress (1.26 GPa).
In addressing the key technical challenges of achieving ultra-broadband and high film-thickness uniformity for meter-class large-aperture space telescopes, this study utilized a self-developed 4 m-class large-aperture thin-film deposition system. By employing plasma-assisted electron-beam evaporation technology and a co-evaporation method with inner and outer dual-ring multi-evaporation sources, precise control of film-thickness uniformity within a 2 m range was achieved. A composite film structure combining a metal reflective layer and an ultraviolet-enhanced dielectric layer was adopted to realize high reflectivity across an ultra-broad spectrum from ultraviolet to long-wave infrared. Experimental results show that the average reflectance of the composite film reaches 91.52% in the 0.25~0.38 μm spectral band and 99.40% in the 0.38~12 μm spectral band. The thickness uniformity of ZrO2 and MgF2 films within the 2 m aperture area was controlled at 1.37% and 3.12%, respectively, meeting the requirements for high uniformity in large-aperture space applications. Radiation testing confirmed that the change in film reflectance is less than 1% under a total irradiation dose of 3.66 × 108 rad(Si), satisfying the demands for operation in harsh space environments. This research provides an innovative solution for thin-film technology in large-aperture, ultra-broad-spectrum space optical systems and holds significant value for engineering applications.
In this study, we propose and fabricate a perfect absorber on a planar substrate using alternate silicon dioxide and ultrathin metallic lossy chromium (Cr) films. Furthermore, we transfer the absorber to a curved substrate via an optimization design of symmetric structures. The absorber exhibits a highly efficient absorption and large incident-angular tolerance characteristics in the whole visible region. We investigate each layer contribution to the absorption theoretically, and find that ultrathin (~5 nm) lossy Cr films play a dominant absorptive role. Using the effective interface method, we calculate the phase difference on the lossy Cr front surface. It is close to the destructive interference condition, from which we clarify why the proposed structures can produce a highly efficient absorption.
To address the challenge of achieving uniform coating on large-aperture substrates with significant sagittal height differences, this study employs a conventional-sized movable sputtering target combined with substrate rotation to realize high-uniformity control. The research establishes a geometric deposition model for the spatial thickness distribution of thin films on large-aperture, high-sagittal-height substrates and develops a precise control method for the deposition distribution on the substrate surface. Using the gradient descent algorithm, an optimal velocity modulation curve is calculated, and the spatial thickness distribution under this curve is determined. Compared with traditional least-squares optimization, this method effectively overcomes the issues of slow computation speed and poor convergence in large-scale numerical calculations, enabling rapid and uniform spatial control of large-aperture substrates. Calculation results demonstrate that the proposed method reduces the film non-uniformity from over 60% to a final value of 2.66%, with a corresponding PV value of 2.61%, across the 6550 mm aperture, showcasing its high precision.