The evolution of the sedimentary environment in the Early Carboniferous Dawuba Formation of the Qiannan Depression significantly controlled the distribution of low-total organic carbon (TOC) sediments. In this study, the core samples were analyzed by thin section microscopy, field emission-scanning electron microscopy, pyrite morphology, X-ray diffraction, and geochemical analysis (TOC, sulfur, organic petrography, and major and trace elements). The formation is vertically divided into two members from bottom to top: Member 1 (average TOC = 1.15%) and Member 2 (average TOC = 0.88%). Depositional environment parameters indicate that Member 1 was in a suboxic-oxic transition environment, with weak detrital influx, and moderate paleoproductivity (more developed algae). Member 2 evolved into a stable oxic environment, with significantly enhanced detrital influx and reduced paleoproductivity. The correlations between multiple geochemical proxies (paleoredox, paleoproductivity, and terrestrial detrital influx) and TOC content indicate that high productivity in Member 1 was the main driver of organic matter accumulation, but the suboxic-oxic environment limited preservation efficiency (1.00% < TOC < 2.00%). Member 2, deposited during sea-level fall, experienced long-term oxic conditions and low productivity due to shallower water. Nevertheless, the partial reduction in the exposure time of organic matter within the oxic water column-driven by rapid detrital accumulation-represents a critical mechanism favoring organic-poor sediments (TOC < 1.00%). In conclusion, the development of low-TOC sediments in the Dawuba Formation reflects a transition from a relatively deep to shallow water column, where the synergistic effects of redox conditions, paleoproductivity, and terrigenous detrital influx controlled the distribution and enrichment of organic matter.

The genesis of authigenic clay minerals in tight sandstones fundamentally controls reservoir quality and micro-pore evolution. This study investigates the differential formation mechanisms of authigenic chlorite and kaolinite and their modulating effects on pore systems in the Chang-8 Member tight sandstones, Ordos Basin. Thin-section petrography, X-ray diffraction, scanning electron microscopy, and high-pressure mercury injection were utilized to quantify mineralogical and petrophysical characteristics. Results show chlorite (averaging 4.8%) and kaolinite (averaging 1.6%) are the dominant authigenic clay minerals with distinct spatiotemporal distributions. Chlorite nucleated as pore linings during early diagenesis under alkaline, oligohaline to mesohaline conditions driven by volcanic material hydration. Conversely, kaolinite precipitated as pore-filling during mid-to-late diagenesis (80–120 °C), driven by organic acid pulses from underlying source rocks causing feldspar dissolution. We conclude that early chlorite linings constructively preserve primary porosity by mechanically resisting compaction and chemically inhibiting quartz cementation, despite narrowing pore throats. Meanwhile, kaolinite acts as a pore-type modulator, restructuring macro-pores into micro-intercrystalline pores, which significantly impairs permeability only when its proportion crosses a critical threshold. The diagenetic fluid transition from alkaline to acidic ultimately dictates this mineralogical succession and subsequent reservoir heterogeneity.

This study investigates the rare-earth element (REE) geochemistry of twenty-nine clastic rock samples from the Paleogene Liushagang Formation in the Weixi’nan Sag. The primary objectives were to quantitatively evaluate the depositional paleoenvironment, determine the provenance lithology, and constrain the tectonic setting of the source area. Results reveal distinct chondrite-normalized REE distribution patterns characterized by light REE (LREE) enrichment, relatively flat heavy REE (HREE) segments, and pronounced negative Eu anomalies. The cerium anomaly index (Ce_anom, normalized to the North American Shale Composite) ranges from −0.06 to 0.00, implying broadly suboxic to anoxic-reducing conditions in the water column during deposition. The chondrite-normalized (La/Yb)_N ratio, utilized as a proxy for relative depositional residence time, decreases stratigraphically from member 3 to member 1, reflecting a transition to shorter residence times and higher relative sedimentation rates. Laterally, (La/Yb)_N increases toward the basin center, accurately recording progressively lower sedimentation rates basinward. Provenance analysis indicates that the sediments were predominantly derived from felsic igneous rocks of the upper continental crust. Spatially, the northern steep-slope belt reflects a uniform source, whereas the southern gentle-slope belt and the Weixi’nan low-uplift periphery record multisource mixed inputs. Finally, tectonic discrimination reveals an “active continental margin” affinity. This geochemical signature represents the inherited tectonic environment of the Mesozoic parent rocks in the surrounding source uplifts, rather than the Cenozoic extensional rift setting of the Weixi’nan Sag itself.

Diagenetic anomalies within the Upper Paleozoic coal-bearing strata of the Longdong area, Ordos Basin, represent a complex interplay between thermal maturation and fluid evolution, yet their governing mechanisms remain poorly understood. This study integrates petrographic analysis, X-ray diffraction, vitrinite reflectance (Ro) measurements, and fluid inclusion microthermometry to evaluate the discrepancy between organic thermal maturity and mineralogical diagenetic records. The results indicate that the mudstones achieved high thermal maturity, with mean Ro and Tmax values of 2.3% and 555.1 °C, respectively. However, the associated sandstones exhibit anomalous mineral assemblages, characterized by persistent high levels of illite/smectite (I/S) mixed-layer minerals and authigenic kaolinite, which are inconsistent with the anticipated advanced diagenetic stage. Furthermore, homogenization temperatures (Th) of fluid inclusions are significantly lower than expected, implying a localized suppression of illitization. We propose that this atypical diagenetic trajectory is governed by sluggish fluid–rock interactions in a confined diagenetic environment. Specifically, the dissolution of feldspars during acidic diagenesis provided a localized Al³⁺ supply, favoring kaolinite precipitation, while the limited availability of reactive feldspar precursors and pore-fluid retention effectively stalled the progression of illitization. These findings demonstrate that reactant availability and reaction kinetics can decouple mineralogical evolution from organic thermal maturation in coal-bearing sequences. This study provides a novel mechanistic framework for interpreting anomalous diagenetic signatures in heterogeneous sedimentary basins, offering significant implications for reservoir quality prediction in deep-seated, thermally mature strata.