A comprehensive analysis of electrical, electromagnetic (EM), mechanical, and thermal properties of epoxy resin composites filled with 0.25–2.0 wt. % of carbon additives characterized by high surface area, both nano-sized, like carbon nanotubes (CNTs) and carbon black (CBH), and micro-sized exfoliated graphite (EG), was performed. We found that the physical properties of both CNTs- and CBH-based epoxy resin composites increased all together with filler content and even more clearly for CBH than for CNTs. In the case of EG-based composites, good correlation between properties and filler amount was observed for concentrations below 1.5 wt. %. We conclude that CBH and, to a lower extent, EG could replace expensive CNTs for producing effective EM materials in microwave and low-frequency ranges, which are, in addition, mechanically and thermally stable.

This research is devoted to the fabrication of polyvinyl alcohol (PVOH) based n-type thermoelectric composites with innovative hybrid bismuth selenide-multiwalled carbon nanotube (Bi₂Se₃-MWCNT) fillers for application in flexible thermoelectric devices. Hybrid fillers were synthesized by direct deposition of Bi₂Se₃ on multiwalled carbon nanotubes using a physical vapor deposition method, thus ensuring direct electrical contact between the carbon nanotubes and Bi₂Se₃. The Seebeck coefficient of prepared PVOH/Bi₂Se₃-MWCNT composites was found to be comparable with that for the Bi₂Se₃ thin films, reaching −100 µV·K⁻¹ for the composite with 30 wt.% filler, and fluctuations of the resistance of these composites did not exceed 1% during 100 repetitive bending cycles down to 10 mm radius, indicating the good mechanical durability of these composites and proving their high potential for application in flexible thermoelectrics. In addition, other properties of the fabricated composites that are important for the use of polymer-based materials such as thermal stability, storage modulus and linear coefficient of thermal expansion were found to be improved in comparison with the neat PVOH.

The current research is devoted to the investigation of the plasticization of polyhydroxybutyrate (PHB) and polyhydroxybutyrate-co-hydroxyvalerate (PHBV) with triethyl citrate (TEC). Three different PHB or PHBV-based systems with 10, 20, and 30 wt.% of TEC were prepared by two-roll milling. The effect of TEC on the rheological, thermal, mechanical, and calorimetric properties of the developed compression-molded PHB and PHBV-based systems was determined. It was revealed that the addition of TEC significantly influenced the melting behavior of both polyhydroxyalkanoates (PHA), reducing their melting temperatures and decreasing viscosities. It was also revealed that all the investigated systems demonstrated less than 2% weight loss until 200 °C and rapid degradation did not occur until 240–260 °C in an oxidative environment. Apart from this, a remarkable increase (ca 2.5 times) in ultimate tensile deformation ε_B was observed by increasing the amount of TEC in either PHB or PHBV. A concomitant, considerable drop in ultimate strength σ_B and modulus of elasticity E was observed. Comparatively, the plasticization efficiency of TEC was greater in the case of PHBV.