Wing–diesel hybrid ships are a practical approach to sustainable maritime transport that harnesses wind energy to supplement diesel propulsion and reduce carbon emissions. The core optimization problem addressed in this study is the global energy efficiency optimization of path planning and propulsion system cooperative control for wing–diesel hybrid ships under two typical sail operation statuses (sail-deployed and sail-stowed) with dynamic changes in complex maritime meteorological and hydrological conditions. To address this issue, this paper proposes a global energy efficiency optimization framework based on an improved Deep Q-Network (DQN) and D*Lite algorithm. Firstly, the D*Lite algorithm is reconstructed with an incremental replanning mechanism and risk-aware cost function to generate real-time safe path constraints. Secondly, the DQN is improved by adopting a dueling network, noisy exploration and prioritized experience replay, and a differentiated reward function dynamically weighted by sail statuses is designed for it. Finally, a fuel consumption prediction model based on the gradient boosting algorithm is integrated into the reward function to realize an accurate energy efficiency assessment. Empirical results confirm that the framework achieves remarkable carbon reduction effects: the optimized routes reduce the total fuel consumption by 5.02%, cut carbon dioxide emissions by 140.66 tons, and improve the energy efficiency operational index by 7.50%. This framework provides an effective technical solution for the dynamic energy efficiency optimization of wing–diesel hybrid ships under different sail operation statuses.