The increasing prevalence of work-related stress requires advanced, non-intrusive physiological monitoring solutions. As conventional methods are often impractical for continuous, real-world applications, this study investigates the deployment of artificial intelligence models on embedded systems for real-time emotion recognition from physiological signals. The study identified critical constraints for embedded implementation, including model size and memory capacity. An evaluation of various machine learning algorithms revealed that, while models like K-Nearest Neighbors (KNN) achieve high accuracy (88.8%), their excessive memory footprints make them unsuitable for resource-constrained hardware. Consequently, Multilayer Perceptron (MLP), Convolutional Neural Network (CNN), Long Short-Term Memory (LSTM), and recurrent neural network (RNN) architectures were deployed on an STM32F411 microcontroller, for which model compression proved essential. An experimental study validated the approach, achieving high recognition rates for pronounced emotions such as hatred (91%) and anger (85%), though with a lower accuracy for more subtle states. These results confirm the potential of embedded AI systems for physiological monitoring, highlighting the critical importance of feature selection and model compression for practical implementation.