The need for pulp and paper has risen significantly due to exponential population growth, industrialization, and urbanization. Most paper manufacturing industries use wood fibers to meet pulp and paper requirements. The shortage of fibrous wood resources and increased deforestation are linked to the excessive dependence on wood for pulp and paper production. Therefore, non-wood substitutes, including corn stalks, sugarcane bagasse, wheat, and rice straw, cotton stalks, and others, may greatly alleviate the shortage of raw materials used to make pulp and paper. Non-woody raw materials can be pulped easily using soda/soda-AQ (anthraquinone), organosolv, and bio-pulping. The use of agricultural residues can also play a pivotal role in the development of polymeric membranes separating different molecular weight cut-off molecules from a variety of feedstocks in industries. These membranes range in applications from water purification to medicinal uses. Considering that some farmers still burn agricultural residues on the fields, resulting in significant air pollution and health issues, the use of agricultural residues in paper manufacturing can eventually help these producers to get better financial outcomes from the grown crop. This paper reviews the current trends in the technological pitch of pulp and paper production from agricultural residues using different pulping methods, with an insight into the application of membranes developed from lignocellulosic materials.

Ethanol production from sugarcane in Brazil is a well-established industry, with relatively simple operations and high yield. The ethanol primarily serves as a renewable fuel blending with gasoline and diesel to increase the energy security in Brazil. Several environmental concerns are emerged around the by-products from this industry. Vinasse, the liquid fraction generated from the rectification and distillation operations of ethanol, is a sulfur-rich, low pH, dark-colored, and odorous effluent, produced at volumes as high as 20 fold of ethanol. Traditional wastewater treatments, such as bioprocessing, advanced oxidative processes, anaerobic digestion, and chemical-based processes, have been applied to vinasse management. Despite most of its utilization being in fertirrigation practices, vinasse may represent a key factor in enhancing profitability and environmental outcomes of a sugarcane-to-ethanol plant. The application of some upgrade solutions to sugarcane-derived vinasse may represent additional sources of energy, production of animal feed components, and reduction in water consumption within a plant. The use of mature technologies, yet not widespread in the sugarcane-to-ethanol industry, could help attenuate environmental concerns. Oxidation and chemical processes, anaerobic digestion, and microbial fermentation have been presented as alternative impactful alternatives to (i) reduce its organic and mineral load, converting it to a feedstock with fewer environmental applications when applied as fertilizer, and (ii) to convert organic matter and nutrients to a nutritious biomass, simultaneously increasing water reclamation potential by plants. This mini-review article provides a critical and comprehensive summary of the alternatives developed or under development to vinasse management.

Heteropolyacids (HPA) with Keggin structures, such as H₃PMo₁₂O₄₀ (H₃PMo), have been described as efficient catalysts in trans/esterifications of high-acid feedstocks due to their tolerance to water and free fatty acids contents.

The establishment of an efficient and feasible biorefinery model depends on, among other factors, particularly the selection of the most appropriate microorganism. Mucor circinelloides is a dimorphic fungus species able to produce a wide variety of hydrolytic enzymes, lipids prone to biodiesel production, carotenoids, ethanol, and biomass with significant nutritional value. M. circinelloides also has been selected as a model species for genetic modification by being the first filamentous oleaginous species to have its genome fully characterized, as well as being a species characterized as a potential bioremediation agent. Considering the potential of replacing several nonrenewable feedstocks is widely dependent on fossil fuels, the exploitation of microbial processes and products is a desirable solution for promoting a green and sustainable future. Here, we introduce and thoroughly describe the recent and critical applications of this remarkable fungus within the context of developing a fungal-based biorefinery.

The production of ethanol from sugarcane or molasses generates vinasse, a residue rich in organic matter and minerals. Vinasse is often used in fertilization and irrigation practices, which may be linked to negative environmental outcomes if excess is applied. Herein, we introduce a novel alternative to the treatment of vinasse promoting the reduction in Chemical Oxygen Demand (COD) levels, phenolic compounds, and its mineral content through the coupling of ozone treatment, anaerobic digestion, and the aerobic growth of fungi. The ozone treatment is able to remove about 30% of the total COD, and deplete the concentration of phenolic compounds, while anaerobic digestion produces biogas and generates vinasse digestate, which is less biorecalcitrant than raw vinasse. The aerobic fungal growth generates oleaginous fungal biomass and promotes over 80% of Kjeldahl-Nitrogen in the vinasse. If vinasse were treated following the sequence of anaerobic digestion, aerobic fungal growth, and ozone treatment, the effluent would have about 95% of the COD decreased, complete removal of phenolic compounds, and over 80% of Kjeldahl-Nitrogen.