There is a lack of literature reporting the measurement and prediction of biochemical methane potential (BMP) of vegetable crop residues (VCRs) and similarly, the kinetic assessment on the anaerobic digestion process of VCR is rarely investigated. In this paper, the BMP tests of five different vegetable (snap bean, capsicum, cucumber, eggplant, and tomato) crop residues were conducted at feed to inoculum ratio (F/I) of 2.0 under mesophilic (36 ± 1 °C) conditions. A series of single-variable and multiple-variable regression models were built based on organic components (hemicellulose, cellulose, lignin, total fat, total sugar, and crude protein) for BMP prediction. Three kinetic models, including the first-order kinetic model, the Chen and Hashimoto model, and the modified Gompertz model, were used to simulate the methane yield results of VCR and obtain valuable model parameters simultaneously. As a result, the BMPs and volatile solids (VS) degradation degree of different VCRs were respectively in the range of 94.2–146.8 mL g⁻¹ VS and 40.4–49.9%; the regression prediction models with variables lignin (R² = 0.704, p = 0.076), variables crude protein and lignin (R² = 0.976, p = 0.048), and variables total fat, hemicellulose, and lignin (R² = 0.999, p = 0.027) showed the best performance on BMP prediction among the single-factor, two-factor, and three-factor models, respectively. In addition, compared to the other two kinetic models, the modified Gompertz model could be excellently fitted (R² = 0.986–0.998) to the results of BMP experiment, verification deviations within 0.3%.

Low-temperature pretreatment (LTPT, Temp. < 100 °C or 140 °C) has the advantages of low input, simplicity, and energy saving, which makes engineering easy to use for improving biogas production. However, compared with high-temperature pretreatment (>150 °C) that can destroy recalcitrant polymerized matter in biomass, the action mechanism of heat treatment of biomass is unclear. Improving LTPT on biogas yield is often influenced by feedstock type, treatment temperature, exposure time, and fermentation conditions. Such as, even when belonging to the same algal biomass, the response to LTPT varies between species. Therefore, forming a unified method for LTPT to be applied in practice is difficult. This review focuses on the LTPT used in different biomass materials to improve anaerobic digestion performance, including food waste, sludge, animal manure, algae, straw, etc. It also discusses the challenge and cost issues faced during LTPT application according to the energy balance and proposes some proposals for economically promoting the implementation of LTPT.

To solve the difficulty of lignocellulose hydrolysis and the formation of crusted scum in anaerobic fermentation, various parts of corn stover, i.e., pith, rind and leaf, were subjected to a two-phase processing including aerobic hydrolysis (AH) and anaerobic fermentation. The results showed that AH significantly broke down the lignin structure of the various components of corn stover and increased the rate of lignin degradation. After 16 h of AH, the lignin degradation rates of the pith, rind and leaf were 4.20%, 3.91% and 4.90%, respectively, and the acetic acid produced accounted for more than 60% of the total amount of volatile fatty acids (VFAs) and ethanol. After hydrolyzing the pith and rind for 12 h and the leaf for 8 h, the maximum methane yields of fresh mass volatile solid (VS) were 323 mL g⁻¹, 251 mL g⁻¹ and 264 mL g⁻¹, respectively, which were increased by 35.02%, 30.05% and 8%, respectively, while the fermentation cycle of T90 (90% of the total gas production) was shortened by 4–5 days. After hydrolyzing the rind and leaf for 12 h and the pith for 16 h, the thicknesses of the scum layer were only 7.1%, 13.6% and 18%, respectively, of that of the untreated group, indicating that AH coupled with anaerobic fermentation can effectively degrade lignin, reduce the thickness of the scum layer and increase the methane yield.

The scum layer of straw anaerobic digestion significantly impacts biogas production efficiency. The initial floating of straw after entering the reactor is an important reason for scum layer formation. Improving the settleability of straw particles and reducing the initial floating time of straw are crucial to suppressing the scum layer, and accelerating the water absorption rate of straw entering the reactor is the key to reducing the floating time. Therefore, in this study the corn stalks were kneaded and rolled, and the stalk particles were tested for water absorption and aerobic hydrolysis. The results showed that the water absorption rate of the stalks after conditioning was significantly accelerated, and the water absorption rate was 120% higher than that of the untreated stalks after absorbing water for 12 h. Simultaneously, aerobic hydrolysis destroys the lignocellulose structure to a certain extent, increases the porosity of the stalk particles, and further improves the settleability of the stalk particles. In the subsequent anaerobic digestion process, scum decreased significantly: the scum layer volume ratio was 13% lower than untreated stalks. The methane production efficiency of anaerobic digestion was significantly improved, and the optimal hydrolysis time was 12 h. At this time, the cumulative methane production of the milled treated stalks reached the maximum value of 319.64 mL/g VS, which was 26.59% higher than that of the untreated stalks.