Solid-state supercapacitors (SSCs) consist of porous carbon electrodes and gel-polymer electrolytes and are used in novel energy storage applications. The current study aims to simulate the impedance of SSCs using a clearly defined equivalent circuit (EC) model with the ultimate goal of improving their performance. To this end, a conventional mathematical and a physicochemical model were adapted. The impedance was measured by electrochemical impedance spectroscopy (EIS). An EC consisting of electrical elements was introduced for each modeling approach. The mathematical model was purely based on a best-fit method and utilized an EC with intuitive elements. In contrast, the physicochemical model was motivated by advanced theories and allowed meaningful associations with properties at the electrode, the electrolyte, and their interface. The physicochemical model showed a higher approximation ability (relative error of 3.7%) due to the interface impedance integration in a more complex circuit design. However, this model required more modeling and optimization effort. Moreover, the fitted parameters differed from the analytically calculated ones due to uncertainties in the SSC’s microscale configuration, which need further investigations. Nevertheless, the results show that the proposed physicochemical model is promising in simulating EIS data of SSCs with the additional advantage of utilizing well-reasoned property-based EC elements.

This paper reports the morphology of a natural patch of Ranunculus penicillatus and presents high-resolution measurements of flow velocities in its wake using a stereoscopic PIV field measurement system. The patch was 3.80 m long, 1.24 m wide and caused substantial changes to downstream mean velocities and turbulence. Vertical profiles of streamwise mean velocity were not logarithmic and flow was redirected under the positively buoyant canopy, enhancing vertical turbulent mixing in the wake and generating a large region where the velocity covariance $\overline{u^{\mathrm{\prime }}{w}^{\mathrm{\prime }}}$ was positive. Turbulent kinetic energy was enhanced downstream from the patch lateral shear layer, but not at the centre of the wake. Spectra downstream from the patch showed that turbulence was neither dominated by fine-scale nor large-scale structures, likely due to the low energy of the flow conditions and lack of a developed vortex street within the measurement domain. Sedimentation was observed at the upstream end of the patch, but not underneath the floating canopy. The methods and results of this work will be useful for planning other in situ studies. Also, the reported data on macrophyte geometry and biometrics will assist with the design of more realistic replicas for use in laboratory studies.

In aero engines, noise absorption is realised by acoustic liners, e.g., Helmholtz resonator (HR) liners, which often absorb sound only in a narrow frequency range. Due to developments of new engine generations, an improvement of overall acoustic damping performance and in particular more broadband noise absorption is required. In this paper, a new approach to increase the bandwidth of noise absorption for HR liners is presented. By replacing rigid cell walls in the liner’s honeycomb core structure by flexible polymer films, additional acoustic energy is dissipated. A manufacturing technology for square honeycomb cores with partially flexible walls is described. Samples with different flexible wall materials were fabricated and tested. The acoustic measurements show more broadband sound absorption compared to a reference liner with rigid walls due to acoustic-structural interaction. Manufacturing-related parameters are found to have a strong influence on the resulting vibration behaviour of the polymer films, and therefore on the acoustic performance. For future use, detailed investigations to ensure the liner segments compliance with technical, environmental, and life-cycle requirements are needed. However, the results of this study show the potential of this novel liner concept for noise reduction in future aero-engines.

Structural supercapacitors (SSCs) are multifunctional energy storage composites (MESCs) that combine the mechanical properties of fiber-reinforced polymers and the electrochemical performance of supercapacitors to reduce the overall mass in lightweight applications with electrical energy consumption. These novel MESCs have huge potentials, and their properties have improved dramatically since their introduction in the early 2000’s. However, the current properties of SSCs are not sufficient for complete energy supply of electrically driven devices. To overcome this drawback, the aim of the current study is to identify key areas for enhancement of the multifunctional performance of SSCs. Critical modification paths for the SSC constituents are systematically analyzed. Special focus is given to the improvement of carbon fiber-based electrodes, the selection of structural electrolytes and the implementation of separators for the development of more efficient SSCs. Finally, current SSCs are compared in terms of their multifunctionality including material combinations and modifications.

The rapidly growing wind industry poses a fundamental problem for wind turbine blade (WTB) disposal in many areas of the world. WTBs are primarily manufactured from composites consisting of a thermoset matrix and reinforcing fibers. Currently, there are no economically viable recycling technologies available for such large-scale composite products. Thus, other treatment strategies for disposed WTBs have to be considered. This study explores the repurpose of WTBs as a promising alternative approach from a processual and technological point of view. For this purpose, the study is guided by the categorization into four different types of repurposed applications: high-loaded complete structure (T1), low-loaded complete structure (T2), high-loaded segmented structure (T3), and low-loaded segmented structure (T4). A three-dimensional CAD model of an Enercon-40/500 (E40) wind turbine blade is derived in a reverse engineering procedure to obtain knowledge about the actual geometry of the WTB. Based on the design, three ecosystems of product scenarios (S) with different manufacturing technologies involved are investigated: a climbing tower (S1), a playground (S2) and the combination of a photovoltaic (PV)-floating pontoon, and a lounger (S3). A screening life cycle assessment (LCA) is conducted to evaluate the three repurposed scenarios according to environmental aspects. It is shown that the repurpose of E40 WTB composite material can reduce the environmental impact and leads to significant resource savings in relation to a reference product of similar quality. A particularly high saving potential is identified for the substitution of emission-intensive materials in construction applications. Furthermore, it is found that transport processes are the primary contributor to the environmental impact of repurposed applications.