Ultrafine Pt nanoparticles were successfully anchored on a polyimide-based covalent triazine framework for the selective hydrogenation of halogenated nitrobenzenes and tandem hydrogenation-coupling reaction to halogenated secondary amines.

The friction behaviors of highly sp ³ -hybridized carbon films, including ultra-nanocrystalline diamond and diamond-like carbon materials, strongly depend on atmospheres.

The quantitative predictions of the photophysical processes for a next generation thermally activated delayed fluorescence (TADF) molecule are calculated by employing the path integral approach to dynamics considering the Herzberg–Teller (HT) and the Duschinsky rotation effects within a multimode harmonic oscillator model. Our theoretical results indicate that thermal activation is no longer a delayed fluorescence issue at T = 300 K for an almost “zero-energy gap” complex with ΔE(¹CT−³CT) ≈ 10 cm⁻¹ between the excited singlet ¹CT(S₁) and triplet ³CT(T₁) states. The direct spin–orbit coupling between the ¹CT and ³CT states is strictly forbidden, and vibronic coupling (i.e., HT effect) is expected to play a critical role in the fluorescence emission, efficient intersystem crossing (ISC) and reverse ISC (RISC) processes. Results show that the fluorescence emission of the molecule possesses enough stability due to the natural vibration modes of the molecule; however, the RISC and ISC rates are still slower, corresponding to values of 4.62 × 10⁴ and 5.57 × 10³ s⁻¹ considering the HT case, respectively. We also found that some energy excited states similar to ^1,3CT can easily mix their character with the ¹CT and ³CT states via multiple coupling routes of zero-field splitting (ZFS) interaction (calculated ZFS parameters, E/D ≈ 1/3), and configuration interaction (nonadiabatic coupling of 5.47 bohr⁻¹ between T₁ and T₂ states), which will greatly accelerate the ISC and RISC processes. The calculated ISC rate of S₁ → T₂ of 1.26 × 10⁵ s⁻¹ is found to be much faster than that of S₁ → T₁ (5.57 × 10³ s⁻¹), and the RISC rate of 7.54 × 10⁸ s⁻¹ of T₂ → S₁ is ∼1000 times faster than the S₁ → T₂ process, which leads to the fact that an emitter, compound 1, can directly harvest all singlet and triplet excitons with the help of the proximate energy excited states without the delayed fluorescence processes. These results are in excellent agreement with the experimental observation of the direct singlet harvesting mechanism, and also will provide a new design concept for the development of TADF molecules.