Against the backdrop of the global aviation industry’s commitment to achieving the “Net Zero Carbon Emissions by 2050” goal, the issue of superimposed peak loads on distribution networks—arising from the large-scale transition from fossil-fueled to electric Ground Service Equipment (GSE) at civil airports—has become increasingly prominent, emerging as a critical constraint on green airport development. Focusing on the high-value airside area, this paper presents the first systematic review of how Vehicle-to-Grid (V2G) technology can transform electric Ground Service Equipment (e-GSE) from mere “charging loads” into “dispatchable energy storage resources.” The study proposes that, through bidirectional DC charging/discharging and intelligent aggregation technologies, e-GSE fleets operating on predictable schedules can be integrated as flexible regulation units within airport microgrids. To realize this pathway, the study comprehensively examines the core technological framework, encompassing wide-power-range bidirectional charging infrastructure, grid-forming power conversion topologies, standardized communication and grid interconnection interfaces, flight-schedule-based potential assessment and dispatch algorithms, and photovoltaic storage–charging hybrid system integration schemes. The review demonstrates that this technology can not only enhance grid resilience and promote renewable energy accommodation through peak shaving, valley filling, and ancillary services but also yields significant economic benefits. Finally, the study identifies the technical, standardization, and business model barriers hindering large-scale deployment, thereby providing a theoretical reference and a technology roadmap for the energy system planning and construction of future “zero-carbon smart airports”.