The pollution on insulators is composed of various chemical components, which threaten the stability of external insulation. However, the existing insulation designs have not taken this issue into consideration. This work aimed to study the influence of pollution chemical components on flashover performance of insulators with various materials. Flashover tests of porcelain, glass and silicone rubber insulators polluted by eight types of common contaminants were conducted. Based on the test data, the influence of chemical components and their solubility on equivalent salt deposit density (ESDD) and insulator flashover performance were analysed; and the electrical properties of different types of insulators were compared. Results show that the ESDD contribution rate changes with chemical components. The dissolution characteristic has a significant influence on the measurement of ESDD; slightly soluble contaminants need to be considered separately. The corresponding insulator flashover gradient for ions can be summarised as Cl ⁻ < NO ₃ ⁻ < SO ₄ ²⁻ , K ⁺ < Na ⁺ , NH ₄ ⁺ < Ca ²⁺ . For a glass insulator, the flashover gradient is 4.9–17.0% higher than that of a porcelain insulator. For a silicone rubber insulator, this gap reaches 14.6–24.4 and 83.3–90% for freely soluble pollution and CaSO ₄ , respectively, this phenomenon can be explained by the combined action of the slightly soluble character of CaSO ₄ and hydrophobicity transference of silicone rubber.

Environmental meteorological parameters (temperature, humidity, air pressure, etc.) have an important impact on short gap streamer discharge. Based on the streamer theory and particle continuity equation of gas discharge, a short gap streamer discharge simulation model is established, and the influence of environmental parameters on the dynamic development process of streamer discharge is simulated and analyzed. The short gap air gap discharge characteristics were tested in a self-made gas discharge chamber. The results show that at low humidity (relative humidity 80%), with the increase of humidity, the electron density of the streamer channel decreases, the field strength of the streamer head decreases, the development speed of the streamer slows down, and the gap breakdown voltage increase. With a decrease of gas pressure, the electron density of the streamer channel decreases, the field strength of the streamer head decreases, the development speed of the streamer increases, and the gap breakdown voltage decreases; The temperature change has little effect on the streamer development process.

Studying the influence of electric field on the icing process of insulators with various dielectric surfaces is of great importance to the design of external insulation. This study established a finite element model to simulate the distribution of electric field around various insulator strings. Energised and non‐energised icing tests were conducted to obtain the influence rules of electric field on the insulator icing process. The results of water droplets freeze experiment provided microscopic explanation of icing tests. Research results indicate that electric field and surface dielectrics have influence on the appearance, density and mass of ice on insulators. In microcosmic view, water droplets on super‐hydrophobic surface correspond to longer freezing time and smaller average diameters, which leads to the better anti‐icing character of super‐hydrophobic insulator. Different types of ice branches appear in the water droplets freezing process on various dielectric surfaces. Owing to the polarisation effect, electric field can inhibit the formation and growth of ice branch, which contributes to different anti‐icing characters of various dielectric surfaces in electric field. The effect of dielectric surface on insulator icing process mainly act at the initial period, surface coatings of insulators are not suggested to be applied in heavily icing area.

With the widespread application of composite insulators in transmission lines, exploring the accumulation mechanism of pollution particles on composite insulator surfaces is of importance to ensure the safe and steady operation of the power system. Addressing the current theoretical shortcomings, this study categorises the accumulation process of particles on the insulator surface into three stages, namely ‘spatial motion’, ‘surface collision’, and ‘surface motion’. The motion and rotation velocities in a multi‐physics field are calculated in the spatial motion stage. In the surface collision stage, a parameter called ‘neck height’ is introduced to determine the optimum mechanics theory, and the normal deposition criterion is established. For the surface motion stage, the sliding displacement and rolling displacement on the surface are calculated based on the rotation speed of the particles. A dynamic pollution accumulation model of the composite insulator is established based on the normal deposition criterion and tangential displacement. Finally, numerical simulations are performed by using the finite element method. Simulation results show that the proposed model agrees with the actual insulator pollution accumulation, and the deposition model is still applicable for various types of composite insulators operating in different applied voltages. The deposition probability of particles increases with the increasing particle size. In the surface motion stage, particle displacement increases with particle size and wind velocity.

Icing can adversely influence electric power system security. Two main issues are caused by icing: the overload of transmission lines, and the reduction in the insulation ability of the insulators. Most previous research has focused on the flashover characteristics of ice-covered insulators, but research on the icing process of the insulator is seriously lacking. Considering the effect of icing shape, the outer airflow field of an insulator was calculated and the local collision efficiencies of water droplets (β₁) were investigated according to the Lagrange algorithm. The simulation showed that the values of β₁ on the insulator edge and rod are much higher than on the insulator surface, and both were significantly influenced by the wind speed and median volume diameter (MVD) of the water droplets. Based on thermal balance equations, a dynamic dry-growth icing model was established. Using the natural icing conditions of Xuefeng Mountain (China) as an example, validation experiments were conducted on a composite insulator and the climate parameters measured by multi-cylinders were used to model the icing shape and mass. The results indicate that high wind speed and low temperature increase icing rate; the icing was mainly concentrated on the windward side and the greatest horizontal thickness was generally on the insulator edge. The dry-growth model had an average error lower than 25% for icing thickness and an average error lower than 20% for icing mass, which were affected by icing roughness.

Low-fired MgTiO₃-based ceramics were fabricated via the conventional solid-state route, and the effects of LiF-doping on their sintering mechanism and microwave dielectric properties were investigated. Addition of 4 wt% LiF enhanced the sinterability of MgTiO₃-based ceramics and effectively lowered the sintering temperatures to 975 °C without degradation of microwave dielectric properties. Optimum microwave dielectric properties of ρ ∼ 3.54 g/cm³, ε_r ∼ 15.5, and Q × f ∼ 34900 GHz were obtained at 975 °C for MgTi_0.95Sn_0.05O₃-4wt%LiF ceramics, which are suitable for LTCC applications.