Traditional vulcanization mold manufacturing is complex, costly, and under pressure due to shorter product lifecycles and diverse variations. Additive manufacturing using Fused Filament Fabrication and high-performance polymers like PEEK offer a promising future in this industry. This study assesses the compressive strength of various infill structures (honeycomb, grid, triangle, cubic, and gyroid) when considering two distinct build directions (Z, XY) to enhance PEEK’s economic and resource efficiency in rapid tooling. A comparison with PETG samples shows the behavior of the infill strategies. Additionally, a proof of concept illustrates the application of a PEEK mold in vulcanization. A peak compressive strength of 135.6 MPa was attained in specimens that were 100% solid and subjected to thermal post-treatment. This corresponds to a 20% strength improvement in the Z direction. In terms of time and mechanical properties, the anisotropic grid and isotropic cubic infill have emerged for use in rapid tooling. Furthermore, the study highlights that reducing the layer thickness from 0.15 mm to 0.1 mm can result in a 15% strength increase. The study unveils the successful utilization of a room-temperature FFF-printed PEEK mold in vulcanization injection molding. The parameters and infill strategies identified in this research enable the resource-efficient FFF printing of PEEK without compromising its strength properties. Using PEEK in rapid tooling allows a cost reduction of up to 70% in tool production.

A non-contact laser polishing method for additively manufactured polymer components with complex three-dimensional geometries is presented, employing a 6-axis robotic system. Robot-guided sample orientation, a quasi-top-hat scanning strategy, and closed-loop temperature control are combined to address curved geometries. On Selective Laser Sintering (SLS)-manufactured Polyamide 12 (PA12) tensile samples with three build orientations and two thicknesses, laser polishing yields up to a 15% increase in tensile strength (Rm) and a 50% increase in elongation at break (A). For 45°-built 5 mm samples, Rm increases from 31.53 MPa to 36.33 MPa and A from 6.52% to 9.8%, approaching the tensile strength reported for optimally oriented SLS-printed PA12 Smooth samples of the same grade. For convex–concave PA12 demonstrators, areal roughness (Sa) on convex surfaces is reduced from 33.6 µm to 2.7 µm (approximately 92%) and the high-pass-filtered micro-roughness (Sa_HP) on concave surfaces by 98.2% to 0.15 µm. For Fused Deposition Modeling (FDM)-printed Polyaryletherketone (PAEK) samples, Sa is reduced from 28.35 µm to 4.1 µm and Sa_HP from 15.98 µm to 0.23 µm (98.6%), despite the high melting temperature and anisotropic raster topography. These results demonstrate that robotic laser polishing constitutes a viable post-processing approach for functionally demanding polymer applications.