Anti-reflective coatings (ARCs) are used to lower the reflection of light on the surface of a substrate. Here, we demonstrate that the two main drawbacks of moth eye-structured ARCs—i.e., the lack of suitable coating materials and a process for large area, high volume applications—can be largely eliminated, paving the way for cost-efficient and large-scale production of durable moth eye-structured ARCs on polymer substrates. We prepared moth eye coatings on polymethylmethacrylate (PMMA) and polycarbonate using wafer-by-wafer step-and-flash nano-imprint lithography (NIL). The reduction in reflection in the visible field achieved with these coatings was 3.5% and 4.0%, respectively. The adhesion of the coating to both substrates was good. The moth eye coating on PMMA demonstrated good performance in three prototypical accelerated ageing tests. The pencil hardness of the moth eye coatings on both substrates was <4B, which is less than required for most applications and needs further optimization. Additionally, we developed a roll-to-roll UV NIL pilot scale process and produced moth eye coatings on polyethylene terephthalate (PET) at line speeds up to two meters per minute. The resulting coatings showed a good replication of the moth eye structures and, consequently, a lowering in reflection of the coated PET of 3.0%.

The building sector contributes approximately one third of the total energy consumption worldwide. A large part of this energy is used for the heating and cooling of buildings, which can be drastically reduced by use of energy-efficient glazing. In this study, we performed building energy simulations on a prototypical residential building, and compared commercially available static (low-e, solar IR blocking) to newly developed adaptive thermochromic glazing systems for various climate regions. The modeling results show that static energy-efficient glazing is mainly optimized for either hot climates, where low solar heat gain can reduce cooling demands drastically, or cold climates, where low-e properties have a huge influence on heating demands. For intermediate climates, we demonstrate that adaptive thermochromic glazing in combination with a low-e coating is perfectly suited. The newly developed thermochromic glazing can lead to annual energy consumption improvement of up to 22% in comparison to clear glass, which exceeds all other glazing systems. Furthermore, we demonstrate that in the Netherlands the use of this new glazing system can lead to annual cost savings of EU 638 per dwelling (172 m², 25% window façade), and to annual nationwide CO₂ savings of 4.5 Mt. Ergo, we show that further development of thermochromic smart windows into market-ready products can have a huge economic, ecological and societal impact on all intermediate climate region in the northern hemisphere.

Methane, which has a high energy storage density and is safely stored and transported in our existing infrastructure, can be produced through conversion of the undesired energy carrier H₂ with CO₂. Methane production with standard transition-metal catalysts requires high-temperature activation (300–500 °C). Alternatively, semiconductor metal oxide photocatalysts can be used, but they require high-intensity UV light. Here, we report a Ru metal catalyst that facilitates methanation below 250 °C using sunlight as an energy source. Although at low solar intensity (1 sun) the activity of the Ru catalyst is mainly attributed to thermal effects, we identified a large nonthermal contribution at slightly elevated intensities (5.7 and 8.5 sun) resulting in a high photon-to-methane efficiency of up to 55% over the whole solar spectrum. We attribute the excellent sunlight-harvesting ability of the catalyst and the high photon-to-methane efficiency to its UV–vis–NIR plasmonic absorption. Our highly efficient conversion of H₂ to methane is a promising technology to simultaneously accelerate the energy transition and reduce CO₂ emissions.

Sunlight‐powered reduction of CO₂ to fuels and chemicals is a promising strategy to close the carbon loop and facilitate the energy transition. In this research, we demonstrate that Au nanoparticles supported on TiO₂ are an efficient plasmonic catalyst for the sunlight‐powered reverse water‐gas shift (rWGS) reaction. A maximum CO production rate of 429 mmol ⋅ g_Au⁻¹ ⋅ h⁻¹ with a selectivity of 98 % and an apparent quantum efficiency of 4.7 % were achieved using mildly concentrated sunlight (1.44 W ⋅ cm⁻² equals 14.4 sun). The CO production rate showed an exponential increase with increasing light intensity, suggesting that the process is mainly promoted by a photothermal effect. Thermal reference experiments with the same catalysts promoted CH₄ formation, dropping the CO selectivity to 70 %. Thus, mildly concentrated sunlight can efficiently and selectively enhance the promotion of the rWGS reaction without using external heating.