To address the environmental pollution caused by nitrogen oxides, V2O5-WO3/TiO2 is widely used as a catalyst based on selective catalytic reduction (SCR) technology. However, spent SCR catalysts pose a potential hazard to the environment due to the presence of heavy metals. This problem continues to plague countries with predominantly thermal power generation, and landfills as the dominant disposal method wastes significant metal resources. Previous research into the recovery of these metal resources has received considerable attention. Here, we summarise the methods of recovery and find that research trends are beginning to move towards improving the added value of recovered products. One very promising application is photocatalysts; however, the atomic efficiency of current methods is not satisfactory. Therefore, this review first focuses on the regeneration of spent SCR catalysts and the processes used for elemental extraction to clarify what forms of V, W and Ti can be obtained from existing processes. This is followed by providing directions for the conversion of spent SCR catalysts into photocatalysts with improvements based on such processes. From a different perspective, this also provides a new resource for photocatalysts and is expected to significantly reduce the cost of photocatalyst production.
Superhydrophobic coatings with intelligent properties have attracted much attention because of their wide application in many fields. However, there is a limited amount of literature on superhydrophobic coatings whose wettability and adhesion can be adjusted by UV irradiation and calcination at the same time. In this study, amorphous SiO2 microspheres (A-SiO2) and nano-TiO2 particles (N-TiO2) were used to fabricate A-SiO2/N-TiO2 composites by wet grinding, and then, they were modified with polydimethylsiloxane (PDMS) and sprayed onto substrate surfaces to obtain a tunable adhesive superhydrophobic A-SiO2/N-TiO2@PDMS coating. It is worth noting that the wettability and adhesion of the coating to water droplets could be adjusted by UV irradiation and calcination. The mechanisms of the aforementioned phenomena were studied. Moreover, methyl orange solution could be degraded by the coating due to its photocatalysis. The as-prepared coating had good adaptation to different substrates and outdoor environments. Moreover, the surfaces of these coatings exhibited the same liquid repellency towards different droplets. This research provides an environmental strategy to prepare advanced self-cleaning coatings.