Wireless sensor nodes (WSNs) for temperature and humidity monitoring are commonly used in a cold chain logistics container. Energy harvesting technology is expected to realize the sustainable self-power supply for the WSN. Low amplitude and broadband vibration energy harvesting performance are the key points in train application. In this study, two piezoelectric vibration energy harvesters (PVEHs) are designed and simulated via COMSOL. Their low resonant frequencies and high electromechanical sensitivities are realized by big L-shaped mass blocks with different material densities. Their broadband vibration energy harvesting performance is achieved by the stopper and series connection. Experimental data are shown at an acceleration of 0.5 m/s2; PVEH-1 and PVEH-2 have maximum powers of 0.24 mW and 0.1 mW when excited at the resonant frequencies of 13.1 Hz and 18.8 Hz, respectively, and they both have the optimal load resistance of 40 kΩ. Two circuit design styles of two PVEHs, independent and series styles, are proposed for broadband vibration energy harvesting. Experimental results show that the series style has a wider operating frequency bandwidth and shorter charging time. Two PVEHs in series style can be effectively used for power supply of the temperature and humidity WSN in the broadband frequency range of 8.7–22.0 Hz above charging root mean square voltage of 5 V at the acceleration of 3.0 m/s2. This scheme is promised to be applied to the cold chain logistics train container.
Two sandwiched ZnO/Metal/ZnO transparent conductive thin films, 50nm ZnO/Cu/50nm ZnO (abbreviated as ZnO(Cu)) and 50nm ZnO/Ti/Cu/Ti/50nm ZnO (abbreviated as ZnO(Ti/Cu)) were deposited by magnetron sputtering technology. The comparative analysis of experiment results shows that the introduction of the Ti layer is beneficial to the overall properties of ZnO(Ti/Cu) thin film compared to ZnO(Cu) thin film with the same metal layer thickness. The effect of the annealing temperature on the performance of the two film systems was studied. Although the carrier concentration did not always increase with annealing temperature, the sheet resistances did decrease due to the obvious increase of mobility. The transmittance of ZnO(Cu) thin films increases with annealing temperature, while that of ZnO(Ti/Cu) films increases at first and then decreases. The optical band gap of ZnO(Cu) thin films increases with temperature, but is lower than that of ZnO(Ti/Cu) thin films, whose bandgap first increases with temperature and then decreases. The figure of merit of the ZnO(Ti/Cu) film is better than that of ZnO(Cu), which shows that the overall performance of ZnO(Ti/Cu) films is better, and annealing can improve the performance of the film systems.
Reduced graphene oxide (rGO) fiber as a carbon-based fiber sensor has aroused widespread interest in the field of gas sensing. However, the low response value and poor flexibility of the rGO fiber sensor severely limit its application in the field of flexible wearable electronics. In this paper, a flexible and wearable nylon fiber sensor modified by rGO and ZnO quantum dots (QDs) is proposed for wide-range NO2 gas detection at room temperature. The response value of the nylon fiber sensor to 100 ppm NO2 gas is as high as 0.4958, and the response time and recovery time are 216.2 s and 667.9 s, respectively. The relationship between the sensor’s response value and the NO2 concentration value is linear in the range of 20–100 ppm, and the fitting coefficient is 0.998. In addition, the test results show that the sensor also has good repeatability, flexibility, and selectivity. Moreover, an early warning module was also designed and is proposed in this paper to realize the over-limit monitoring of NO2 gas, and the flexible sensor was embedded in a mask, demonstrating its great application potential and value in the field of wearable electronics.
A Mach–Zehnder fiber optic sensor with high refractive index response sensitivity was developed. By fabricating a waist-enlarged bitaper structure on the interference arm of a single mode–multimode–single mode (SMS) Mach–Zehnder interferometer (MZI), the spectral contrast and response sensitivity were improved. Subsequently, the response sensitivity was further improved by etching the interference arm. When a beam of light was introduced into the sensor, due to the structural mismatch between the multimode fiber and the normal transmission light, the difference between the low-order mode and the high-order mode was generated in the fiber core and the fiber cladding. In the process of transmission in the sensing arm, due to the different refractive indices of the core and cladding, the optical path difference of the high-order mode and the low-order mode was different, which eventually generated interference fringes. The experimentally measured response sensitivity of SMS MZI in the range of 1.351 RIU to 1.402 RIU is 57.623 nm/RIU; the response sensitivity of a single mode–multimode–bitaper–multimode–single mode (SMBMS) MZI is 61.607 nm/RIU; and the response sensitivity of the etched SMBMS (ESMBMS) MZI is 287.65 nm/RIU. The response sensitivity of the new ESMBMS MZI is three times higher than that of the original SMS MZI. The sensor has the characteristics of compact structure, high sensitivity, easy manufacture, and a wide range of refractive index measurements, and can be used in food processing, pharmaceutical manufacturing and other fields.
At present, flexible pressure-sensitive materials generally have problems with weak adhesion and poor wear resistance, which easily result in friction failure when used for plantar pressure detection. In this study, a flexible pressure sensor with the advantages of a wide detection range, fast recovery, and good abrasive resistance was designed and prepared based on the screen printing process. The pressure-sensitive unit with a structural size of 5 mm× 8 mm was a functional material system due to the use of graphene and epoxy resin. The influence of the different mass ratios of the graphene and epoxy resin on the sensing properties was also studied. The test results showed that when the mass ratio of graphene to epoxy resin was 1:4, the response time and recovery time of the sensing unit were 40.8 ms and 3.7 ms, respectively, and the pressure detection range was 2.5–500 kPa. The sensor can detect dynamic pressure at 0.5 Hz, 1 Hz, 2 Hz, 10 Hz, and 20 Hz and can withstand 11,000 cycles of bending. In addition, adhesion tests showed that the high viscosity of the epoxy helped to improve the interlayer bond between the pressure-sensitive materials and the flexible substrate, which makes it more suitable for plantar pressure detection environments, where friction is common.
Extrinsic optical fiber Fabry–Perot (F–P) high temperature sensors using Al2O3 ceramic tubes were fabricated by a microscope equipped with a CCD whose scaleplate has been calibrated using a standard gauge block. The initial cavity length of the F–P sensor, which must be larger than 36 µm, whose output signal is demodulated by the multi-peak method is determined. The temperature measurement range of the sensor is 25 °C–1000 °C. Because the temperature sensitivity of the F–P temperature sensor made by Al2O3 ceramic tubes, whose thermal expansion coefficient is different from that of the fiber, is dependent on the initial cavity length, a low initial cavity length is beneficial in improving sensor sensitivity. Compared with the results of the quartz tube F–P sensor, the temperature sensitivity of the ceramic tube F–P sensor is 10 times larger than that of the quartz tube F–P sensor. Hence, it can be deduced that the ceramic tube F–P sensor is greatly improved compared with the quartz tube F–P sensor.