This study investigates the effect of potassium ion (K+) concentration on double helix aggregation in κ-carrageenan-based hydrogels, which significantly influences their shakedown behavior. The shakedown behavior of κ-carrageenan/polyacrylamide (PAAm) hydrogels was characterized by the evolution of maximum stress and energy dissipation during cyclic load. The experimental results indicate that higher K+ concentrations significantly improve the maximum stress in the steady state, but barely influence the energy dissipation in the steady state. The improved maximum stress can be explained by the higher density of double helix aggregation. The steady energy dissipation elucidates that the K+ concentration does not affect the breaking–recovering balance of the sacrificial network in cyclic loading. These results provide mechanistic insights into how ion-triggered double helix aggregation influences the shakedown behavior of κ-carrageenan-based hydrogels.
We proposed an aperiodic laser beam distribution, in which the laser beams are placed along a Fermat spiral, to suppress the sidelobe power in the coherent beam combining. Owing to the changed distances between two consecutive beams, the conditions of the sidelobe suppression are naturally satisfied. The Fermat spiral array was demonstrated to achieve a better sidelobe suppression than the periodic arrays, and the effects of various factors on the sidelobe suppression were analyzed numerically. Experiments were carried out to verify the sidelobe suppression by different Fermat spiral arrays, and the results matched well with the simulations.
The interaction between nonmetal and metal atoms has attracted great interest in the development of organometallic compounds and their promising applications. In this study, we explored the interaction between boron and thorium atoms, based on the stable B40Th coordination compound, by employing density functional theory calculations. We elucidated the stability and geometries of the B40Th coordination compound and revealed the electron transfer from the metal atom Th to B40, which is evidenced by the natural bond orbital calculations. This electron transfer is attributed to the electron-withdrawing character of the boron atom and results in clear electrostatic interaction. Additionally, bond critical analysis and bond order calculations show obvious covalent characters between the metal and nonmetal atoms. The IR spectrum was simulated to give detailed information to identify this targeted compound in future experiments. This study is expected to enhance the understanding of metal–nonmetal interactions and provides useful information for constructing new organometallic compounds based on actinium metal atoms.
Ionogels combining ionic liquids with polymer networks show promise for flexible electronics, but their mechanical and functional performance often needs enhancement. Here, we report a series of magnetic nanocomposite ionogels fabricated by doping triiron tetraoxid (Fe3O4) nanoparticles into a [C2mim]+[EtSO4]−-dispersed cross-linked PAA matrix. The effect of PAA content (10–20 wt%) on the optical, mechanical, and dielectric properties of pure imidazolium ionogels was first investigated. Increasing PAA concentration enhanced tensile strength (up to ~0.7 MPa) and compressive modulus (~0.65 MPa) while reducing optical transmittance; dielectric relaxation peaks around 6–8 GHz were observed, with the 15 wt% sample showing the highest permittivity. Subsequently, Fe3O4 nanoparticles (0–20 wt%) were incorporated into the 10 wt% PAA ionogel. The resulting magnetic ionogels exhibited reduced tensile strength, but significantly increased elongation (up to ~12 strain), indicating network softening. Magnetic hysteresis measurements confirmed superparamagnetic behavior with saturation magnetization reaching ~2.5 emu/g at 20 wt% Fe3O4 loading. This work demonstrates a facile strategy to simultaneously tune mechanical, dielectric, and magnetic properties in imidazolium ionogels, providing guidelines for designing soft multifunctional materials for microwave absorption, magnetic actuation, and flexible sensor applications.
To enhance the distinct military characteristics of our university, this study explores the integration of Rocket Force-specific military applications into our college physics curriculum. The research involves refining and distilling military cases related to missile weaponry and incorporating them precisely into the instructional content. An innovative teaching model that combines Problem-Based Learning (PBL) with an Iterative Content Application Development (IAD) cycle has been adopted, along with the implementation of smallgroup seminars on the military applications of missile technology and research-oriented assignments on military themes. Practice has demonstrated that these measures effectively enhance students' scientific literacy, military competence, and problem-solving capabilities, thereby improving overall teaching quality. This study offers valuable references for the reform of college physics education in military academies and the cultivation of high-quality military talent.