Copper (Cu) was used in antiquity to prevent waterborne and food diseases because, as a broad-spectrum antimicrobial agent, it generates reactive oxygen species, ROS.

Studies related to biomass production, with a focus on energy uses for short-rotation woody crops (SRWCs), are limited in Latin America. The research that is available relates to a variety of tested SRWC species (50 species), however, the most important species are Populus, Salix, Eucalyptus, Acacia, and Gmelina arborea. In the existing studies, stocking densities varied from 1111 to 20,000 trees per hectare, with square or rectangular spacing. One important advantage of SRWC systems in this region, compared to most regions worldwide, is the predictability of biomass yields due to the tropical climate conditions of the majority of the Latin American countries. Rotations of three and four years can be projected to produce total biomass yields of 30–50 tons/ha, with increments of 10–20 tons/ha/yr. Fertilization is performed in SRWC with the aim of preventing soil degradation and maintaining further production. In regards to possible uses of biofuel generated from SRWC in Latin America, an inconvenience is that there are neither well-established harvesting systems nor conventional pre-treatments to process the biomass. Processes that are available in the region that use biomass from SRWC for energy production are gasification and pellet production. Other potential biofuel processes, such as torrefaction and biochemical conversion, are limited in this area.

Our long-term goal is to develop a hybrid cellulose-copper nanoparticle material as a functional nanofiller to be incorporated in thermoplastic resins for efficiently improving their antimicrobial properties. In this study, copper nanoparticles were first synthesized through chemical reduction of cupric ions on TEMPO nanofibrillated cellulose (TNFC) template using borohydride as a copper reducing agent. The resulting hybrid material was embedded into a polyvinyl alcohol (PVA) matrix using a solvent casting method. The morphology of TNFC-copper nanoparticles was analyzed by transmission electron microscopy (TEM); spherical copper nanoparticles with average size of 9.2 ± 2.0 nm were determined. Thermogravimetric analysis and antimicrobial performance of the films were evaluated. Slight variations in thermal properties between the nanocomposite films and PVA resin were observed. Antimicrobial analysis demonstrated that one-week exposure of nonpathogenicEscherichia coliDH5αto the nanocomposite films results in up to 5-log microbial reduction.

Biodegradable polymers hold great therapeutic value, especially through the addition of additives for controlled drug release. Nanocellulose has shown promise in drug delivery, yet usually requires chemical crosslinking with harsh acids and solvents. Nanocellulose fibrils (NFCs) and 2,2,6,6-tetramethylpiperidine-N-oxyl (TEMPO)-mediated oxidized nanocellulose fibrils (TNFCs) with poly (vinyl alcohol) (PVA) could be aqueously formulated to control the release of model drug acetaminophen over 144 h. The release was evaluated with a multiphase release mechanism to determine which mechanism(s) contribute to the overall release and to what degree. Doing so indicated that the TNFCs in PVA control the release of acetaminophen more than NFCs in PVA. Modeling showed that this release was mostly due to burst release—drug coming off the immediate surface, rather than diffusing out of the matrix.

Micro- and nanofibrillated cellulose (MNFC) was extracted from pineapple stems by acid hydrolysis, then characterized and tested in two concentrations (0.5 and 1.0 wt%) in polyvinyl acetate (PVAc) and urea-formaldehyde (UF) adhesives. The modified adhesives were used to glue three tropical wood species (Vochysia ferruginea,Cordia alliodora, andGmelina arborea), and their corresponding bond strength resistance was determined. MNFC and the correspondent adhesives were characterized by TGA, FTIR, SEM, TEM, AFM, and viscosity determination. The TGA analysis of MNFC showed three decomposition reactions. The SEM, TEM, and AFM evaluations demonstrated the presence of micro- and nanosized dimensions of particles after the acid hydrolysis of pineapple stems. Adding 1 wt% MNFC to PVAc and UF adhesives increased their thermal stability in similar manner. Viscosity diminished in both modified adhesives with MNFC; however, this reduction did not affect the adhesion properties in the tropical wood tested. MNFC added to PVAc and UF adhesives improved shear strength (SS) of the glue line in the three tropical species tested. The highest SS increase was obtained when adding 0.5 wt% MNFC to PVAc inV. ferruginea, and 1 wt% MNFC concentration in the case ofC. alliodoraandG. arborea. In the case of UF adhesives, the application of 1 wt% MNFC produced significant differences in SS for the three tropical species studied.

Torrefaction Kinetics of Red Oak (Quercus rubra) in a Fluidized Reactor