As the largest freshwater lake in China, water environmental pollution in Poyang Lake is increasingly attracting attention. However, to date, the occurrence of seldom-monitored trace elements (SMTEs) (such as thallium (Tl) and cobalt (Co)) and their potential ecological influences in the Poyang Lake area remain unclear. Here, geochemical baseline concentrations (GBCs) were employed to investigate anthropogenic inputs of these two metals (Tl and Co) and were used to assess the potential ecological risk in surface sediments of Poyang Lake. The results showed that the mean concentrations of Tl and Co were 1.11 mg/kg and 15.42 mg/kg, respectively, slightly higher than background values (BVs) in local soil. Spatially, the Co concentrations in surface sediments of Poyang Lake varied; Co concentrations in the west of the study area were significantly lower than in the middle of the lake. In contrast, no significant spatial variation of Tl was found in studied areas of Poyang Lake. Average GBCs were similar to the mean measured concentrations of Tl and Co in the lake, and both were higher than the BVs in local soil. In anthropogenic source analysis based on the GBCs, 47.22% samples and 41.67% samples were influenced by human activity for Tl and Co, respectively; the mean anthropogenic contribution rate was 5.90% for Tl (0.43 to 16.22%), and 13.01% for Co (0.82 to 31.59%). These results indicated that Tl and Co mainly originate from natural processes. However, the anthropogenic contribution should not be ignored. Moreover, the geo-accumulation index (I_geo) and potential ecological parameter (E_r) generally indicated no contamination and a low potential risk for Tl and Co in Poyang Lake sediments, which used the GBCs as BVs. The results of this study suggest that GBCs are more scientifically robust and practical as a reference than BVs. They can also be used when BVs are lacking.

This study investigated the concentrations and spatial distributions, ecological risks, and potential pollution sources of potential toxic elements (PTEs) in the soils and sediments collected from the Guishui River (GSR) in Beijing, China. Multiple methods for pollution assessment and source identification of PTEs in the sediments/soils were used, including analysis of the physicochemical properties, Geo-accumulation index (I_geo), potential ecological risk index (RI), Pearson correlation, principal component analysis (PCA), and Pb isotopic ratio analysis. The results showed that PTE concentrations in the sediments/soils were similar to the soil background values (BV) of Beijing, except for Cd. Maximum Cd concentrations in soils were far below the guideline of the Environmental Quality Standard for Soils in China. PTE concentrations in the soils were slightly higher than those in the sediments. Upstream to downstream of GSR, PTEs concentrations in the soils and sediments remained stable. Pollution assessment based on I_geo and RI indicated that Cd was the main contaminant with moderate pollution levels. PCA results showed that Cd originated from anthropogenic sources, mainly including pesticide and fertilizer residues, while other metals mainly originated from natural sources. Further source identification using Pb isotopic ratios and PCA indicated that Cu, Pb, and Zn in GSR originated from anthropogenic sources (aerosols and coal combustion) and atmospheric deposition was considered as the primary input pathway.

Simultaneous ecological and health risk assessments of potentially toxic elements in soils and sediments can provide substantial information on their environmental influence at the river-basin scale. Herein, soil and sediment samples were collected from the Guishui River basin to evaluate the pollution situation and the ecological and health risk of potentially toxic elements. Various indexes were utilized for quantitatively assessing their health risks. Pollution assessment by geo-accumulation index showed that Cd had “uncontaminated to moderately polluted” status in the soils and sediments. Potential ecological risk index showed that the Guishui River basin was at low risk in general, but Cd was classified as “moderate or considerable ecological risk” both in the soils and sediments. Health risk assessment calculated human exposure from soils and indicated that both non-carcinogenic and carcinogenic risks of the selected potentially toxic elements were lower than the acceptable levels. Health risks posed by potentially toxic elements bio-accumulated in fish, stemming from sediment resuspension, were also assessed. Non-carcinogenic hazard index indicated no adverse health effects on humans via exposure to sediments; however, in general, Cr contributed largely to health risks among the selected potentially toxic elements. Therefore, special attention needs to be paid to the Guishui River basin in the future.