This work reports the successful preparation of nanoporous iron oxide/carbon composites through the in-situ growth of Prussian blue (PB) nanoparticles on the surface of graphene oxide (GO) nanosheets. The applied thermal treatment allows the conversion of PB nanoparticles into iron oxide (Fe₂O₃) nanoparticles. The resulting iron oxide/carbon composite exhibits higher specific capacitance at all scan rates than pure GO and Fe₂O₃ electrodes due to the synergistic contribution of electric double-layer capacitance from GO and pseudocapacitance from Fe₂O₃. Notably, even at a high current density of 20 A g⁻¹, the iron oxide/carbon composite still shows a high capacitance retention of 51%, indicating that the hybrid structure provides a highly accessible path for diffusion of electrolyte ions.

Herein, we demonstrate the bottom-up synthesis of 2D cyano-bridged Cu-Ni coordination polymer (CP) nanoflakes through a controlled crystallization process and their conversion to Cu-Ni mixed oxides via a thermal treatment in air. The chelating effect of citrate anions effectively prevents the rapid coordination reaction between Cu²⁺ and K₂[Ni(CN)₄], resulting in the deceleration of the crystallization process of CPs. Specifically, with addition of trisodium citrate dehydrate, the number of nuclei formed at the early stage of the reaction is decreased. Less nuclei undergo a crystal growth by interacting with [Ni(CN)₄]²⁻, leading to the formation of larger Cu-Ni CP nanoflakes. Following heat treatment in air, the -CN- groups present within the CP nanoflakes are removed and nanoporous Cu-Ni mixed oxide nanoflakes are generated. When tested as an electrode material for supercapacitors using a three-electrode system, the optimum Cu-Ni mixed oxide sample shows a maximum specific capacitance of 158 F g⁻¹ at a current density of 1 A g⁻¹. It is expected that the proposed method will be useful for the preparation of other types of 2D and 3D CPs as precursors for the creation of various nanoporous metal oxides.