Mechanical activation of granulated copper slag (GCS) is carried out in the present study for the purposes of enhancing pozzolanic activity for the GCS. A vibration mill mills the GCS for 1, 2, and 3 h to produce samples with specific surface area of 0.67, 1.03 and 1.37 m²/g, respectively. The samples are used to replace 30% cement (PC) to get 3 PC-GCS binders. The hydration heat and compressive strength are measured for the binders and derivative thermogravimetric /thermogravimetric analysis (DTG/TGA), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM) are used to characterize the paste samples. It is shown that cumulative heat and compressive strength at different ages of hydration and curing, respectively, are higher for the binders blending the GCS milled for a longer time. The compressive strength after 90 d of curing for the binder with the longest milling time reaches 35.7 MPa, which is higher than the strength of other binders and close to the strength value of 39.3 MPa obtained by the PC pastes. The percentage of fixed lime by the binder pastes at 28 days is correlated with the degree of pozzolanic reaction and strength development. The percentage is higher for the binder blending the GCS with longer milling time and higher specific surface area. The pastes with binders blending the GCS of specific surface area of 0.67 and 1.37 m²/g fix lime of 15.20 and 21.15%, respectively. These results together with results from X-ray diffraction (XRD), FTIR, and SEM investigations demonstrate that the mechanical activation via vibratory milling is an effective method to enhance the pozzolanic activity and the extent for cement substitution by the GCS as a suitable supplementary cementitious material (SCM).

Cemented paste backfill (CPB), a technology placing the solid waste into mined-out stopes in the mine through pipeline transportation, has been widespread all over the world. The resistance loss is an important parameter for pipeline transport, which is significantly affected by the slurry characteristics. However, the coupling effect of inlet velocity (IV), particle mass concentration (PMC), and particle size (PS) has not been well evaluated and diagnosed. Hence, the CFD-based three-dimensional network simulation of CPB slurry flow in an L-shaped pipe at different combinations of the three parameters was developed using COMSOL Multiphysics software, and the findings were validated through a loop experiment. The results show that increasing IV and reducing PS will contribute to the homogeneity of the slurry in the pipeline, while the PMC presents little effect. The pipe resistance loss is positively correlated with IV and PMC and negatively correlated with PS. The sensitivity to the three parameters is IV > PS > PMC. In particular, the resistance loss is minimal at IV of 1.5 m/s, PMC of 72%, and PS of 1000 um. The calculation model of resistance loss regressed from simulation presented a high accuracy with an error of 8.1% compared with the test results. The findings would be important for the design of the CPB pipeline transportation and provide guidance in the selection of transfer slurry pumps, prepreparation of backfill slurry, and pipe blockage, which will improve the safety and economic level of a mine.

The application of granulated copper slag (GCS) to partially replace cement is limited due to its low pozzolanic activity. In this paper, reconstituted granulated copper slag (RGCS) was obtained by adding alumina oxide (Al₂O₃) to liquid copper slag. Blended cement pastes were formulated by a partial substitute for ordinary Portland cement (OPC) with the RGCS (30 wt%). The pozzolanic activity, mechanical development, and the microstructure were characterized. The results show that 5–10 wt% Al₂O₃ contributes to the increase in magnetite precipitation in RGCS. The addition of Al₂O₃ alleviates the inhibition of C₃S by RGCS and accelerates the dissociation of RGCS active molecules, thus increasing the exothermic rate and cumulative heat release of the blended cement pastes, which are the highest in the CSA10 paste with the highest Al₂O₃ content (10 wt%) in RGCS. The unconfined compressive strength (UCS) values of blended cement mortar with 10 wt% Al₂O₃ added to RGCS reach 27.3, 47.4, and 51.3 MPa after curing for 7, 28 and 90 d, respectively, which are the highest than other blended cement mortars, and even exceed that of OPC mortar at 90 d of curing. The pozzolanic activity of RGCS is enhanced with the increase in Al₂O₃ addition, as evidenced by more portlandite being consumed in the CSA10 paste, forming more C-S-H (II) gel with a higher Ca/Si ratio, and a more compact microstructure with fewer pores than other pastes. This work provided a novel, feasible, and clean way to enhance the pozzolanic activity of GCS when it was used as a supplementary cementitious material.