Asphalt mixture is the most widely used material in road construction, and the industry is developing more sustainable technologies. Warm mix asphalt (WMA) is a promising alternative as it saves energy, reduces fuel consumption and generates fewer gas and fume emissions, while maintaining a similar performance to hot mix asphalt (HMA). This paper presents an evaluation of the gas emissions at laboratory scale, as well as the energy consumption and production costs, of five types of WMA with the addition of natural zeolite. The control mixture was a HMA manufactured at 155 °C. The mixtures evaluated were two WMA manufactured at 135 °C with 0.3% and 0.6% natural zeolite, and three WMA with partial replacement of raw materials by 10%, 20% and 30% of reclaimed asphalt pavement (RAP); these mixtures, called WMA–RAP, were manufactured at 125 °C, 135 °C and 145 °C, respectively. The results indicated that all the mixtures evaluated reduced CO and CO₂ emissions by 2–6% and 17–37%, respectively. The energy consumption presented a 13% decrease. In the current situation, the production costs for WMA with 0.3 and 0.6% natural zeolite are slightly higher than the control mixture, because the saving achieved in fuel consumption is lower than the current cost of the additive. On the other hand, WMA manufactured with the addition of natural zeolite and RAP could produce cost savings of up to 25%, depending on the amounts of RAP and natural zeolite used.

Conventional asphalt mixtures used for road paving require high manufacturing temperatures and therefore high energy expenditure, which has a negative environmental impact and creates risk in the workplace owing to high emissions of pollutants, greenhouse gases, and toxic fumes. Reducing energy consumption and emissions is a continuous challenge for the asphalt industry. Previous studies have focused on the reduction of emissions without characterizing their composition, and detailed characterization of volatile organic compounds (VOCs) and semi-volatile organic compounds (SVOCs) in asphalt fumes is scarce. This communication describes the characterization and evaluation of VOCs and SVOCs from asphalt mixtures prepared at lower production temperatures using natural zeolite; in some cases, reclaimed asphalt pavement (RAP) was used. Fumes were extracted from different asphalt mix preparations using a gas syringe and then injected into hermetic gas sample bags. The compounds present in the fumes were sampled with a fiber and analyzed by gas-liquid chromatography coupled to mass spectrometry (GC/MS). In general, the preparation of warm mix asphalts (WMA) using RAP and natural zeolite as aggregates showed beneficial effects, reducing VOCs and SVOCs compared to hot mix asphalts (HMA). The fumes captured presented a similar composition to those from HMA, consisting principally of saturated and unsaturated aliphatic hydrocarbons and aromatic compounds but with few halogenated compounds and no polycyclic aromatic hydrocarbons. Thus, the paving mixtures described here are a friendlier alternative for the environment and for the health of road workers, in addition to permitting the re-use of RAP.

Today, an important part of paved surfaces in the world uses asphalt mixtures. This practice increases the use of aggregates and fossil fuels, the availability of which is limited. Most of the studies referring to asphalt mixtures reported and compared the mechanical performances without detailing the environmental impacts of the different technologies proposed. The objective of this study was to present and compare through a life cycle assessment using a “cradle-to-gate” approach of different types of asphalt mixtures designed for the same performance, hot mix asphalt (HMA) as a control sample, and warm mix asphalt (WMA) using natural zeolite, Evotherm^® and reclaimed asphalt material (RAP) in different proportions. The analysis was performed using SimaPro 9 software, using the ReCiPe method version 1.11. For the comparison of the environmental impacts, 1 ton of asphalt mixture was used as a functional unit. The most relevant results show that the use of natural zeolite or Evotherm^® helps to reduce environmental impacts. In the global warming impact category, the decrease between the standard HMA and a mix with RAP and natural zeolite was 8%, while in the fossil fuel depletion, the decrease was 13%.

The purpose of this study was to verify the feasibility of using biochar from oat hulls (BO) as a potential bio-modifier to improve the physical properties of conventional asphalt binder. The BO and asphalt binder were characterized by confocal (fluorescence) laser microscopy, scanning electron microscopy and Fourier transform infrared spectroscopy. Then, an asphalt binder modification procedure was established and modifications with 2.5, 5.0 and 7.5% of BO on the weight of the asphalt binder were evaluated, using a particle size < 75 µm. The physical properties of the evaluated modified asphalt binder with BO were: rotational viscosity in original and aged state, aging index, Fraass breaking point, softening point, penetration, penetration rate and storage stability. The results indicated that the BO has a porous structure, able to interact with the asphalt binder by C=O and C=C bonds. In addition, modification of the asphalt binder with BO increases the rotational viscosity related to high-temperature rutting resistance. The results obtained from the Fraass breaking point and softening point indicated that the use of BO extends the viscoelastic range of the asphalt binder. In addition, the evaluated modifications present low susceptibility to aging and good storage stability.

In this study, the effect of biochar from oat hulls (BO) on the rheological properties of a PG 64-22 asphalt binder was evaluated using a full factorial design, which included the following factors: pyrolysis temperature (PT) (300 °C and 500 °C), BO particle size (<20 µm and <75 µm), and the amount of BO (2.5%, 5%, and 7.5%). First, the morphological and physicochemical properties of BO were analyzed by comparing it with graphite powder (CFG) and commercial activated carbon (CAC). The physicochemical properties of the modified asphalt binder were then evaluated using confocal laser microscopy, scanning electron microscopy (SEM–EDX), and Fourier-transform infrared spectroscopy (FTIR). Its storage stability was also evaluated. Subsequently, the rutting parameter G*/sin(δ) and the Fraass breaking point were analyzed to select asphalt binders that extended their viscoelastic range. The asphalt binders selected were those with 2.5%, 5%, and 7.5% BO, produced at a PT of 300 °C with a particle size <20 µm (BO300S). Next, the rheological properties of the selected samples were evaluated by testing for rotational viscosity, rutting parameter G*/sin(δ), multiple stress creep recovery (MSCR), fatigue parameter G*·sin(δ), and creep stiffness by bending beam rheometry (BBR). The rheological aging index according to rutting parameter G*/sin(δ) (RAI) was also evaluated. These tests were conducted in different states of the asphalt binder: original, short-term aged, and long-term aged. According to the results, the application of BO300S significantly increased the resistance of the asphalt binder to rutting and rotational viscosity, proportional to the amount added to the asphalt binder. Moreover, low modifier percentages improved fatigue resistance, outperforming CFG and CAC. In addition, it performs well at low service temperatures, registering better resistance than the control asphalt binders.

In most cases, stone mastic asphalt (SMA) mixtures placed in thin layers and subjected to stress develop early cracks (potentially resulting from being improperly affixed to the underlying layer, placed over previously cracked asphalt pavement, or placed over Portland cement concrete slabs). However, the filler used in SMA production is very influential on the performance of the mix. Fillers used in this type of mixture have a low plastic index or are inert (calcium carbonate or lime), so it is important to understand the effect of each material on the possible fissuring and cracking process of the SMA mixture. The objective of this study is to present an evaluation of the behavior of SMA asphalt mixtures with different types of filler and at different temperatures using the semicircular bend (SCB) fracture energy test. This research compares results between fracture energy and different types of filler in SMA asphalt mixtures at temperatures ranging from −10 to 25 °C.