Hydrothermal co-liquefaction of mixed (wet and dry) biomass residue streams would greatly enhance the viability and scale up potential of the technology as platform in bioenergy and biorefinery applications. This study aims to identify possible interaction effects between three different feeds (protein-rich microalgae, lignocellulosic wood, and carbohydrate-rich sugar beet pulp) and to broaden the data set for evaluating this concept. Co-liquefaction was evaluated at 250 and 350 °C at 10 min of holding time, using 10 wt%( in water) binary mixtures (1:1 wt basis) and a (1:1:1 wt basis) ternary mixture. Results show that interaction during co-liquefaction does play a role and especially reduced the amount of biocrude produced. The biocrude yields obtained are around 15 and 40% below the estimated values for binary and ternary mixtures, on basis of linear averaging the results for the single feeds. For mixtures including algal biomass, a more than proportional nitrogen content and fraction of high molecular mass components was found in the biocrude. For the predictability of biocrude yield and composition in case of biomass mixtures, more work is needed to unravel these interactions.
Airborne microplastic is an emerging and widespread pollutant yet is still under-characterised and insufficiently understood. Detailed description of microplastic air pollution is crucial as it has been identified in human lungs and remote locations, highlighting the atmosphere as a medium of MP dispersion and transportation. The lack of standardization of methods for measuring and further monitoring of microplastic pollution is an obstacle towards assessment of health risks. Since the first recognition of MP presence in the atmosphere of Krakow in 2019, this research was conducted to further characterise and develop the methods for qualitative and quantitative analysis of airborne microplastic (attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR); pyrolysis-gas chromatography–mass spectrometry (Py-GC–MS); scanning electron microscopy-energy dispersive spectroscopy SEM-EDS) and pre-treatment of samples. The data were gathered in seven cycles from June 2019 to February 2020. The methods used in the study allowed the identification and analysis of the changing ratio of the different types of synthetic polymers identified in the atmospheric fallout (low-density polyethylene, nylon-66, polyethylene, polyethylene terephthalate, polypropylene and polyurethane). Observations of interactions between microplastic particles and the environment were conducted with analyses of surface changes due to degradation. Different phases attached to the microplastics surfaces, with some of the inorganic contaminants transported on these surfaces determined also to be of anthropogenic origin. The methodology proposed in this study allows further characterisation of microplastic from multiple locations to provide highly comparable data, leading to identification of the sources of this phenomenon, as well as seasonal changes.