The consolidation properties of soil-bentonite (SB) backfills containing 20% of the weight of sodium-hexametaphosphate-modified calcium bentonite (SHMP-20CaB) and prepared with 0 mM to 1000 mM calcium chloride (CaCl2) solution were evaluated. The results indicated that both consolidation stress and CaCl2 concentration had significant effects on the consolidation behaviors of the SHMP-20CaB backfill. In general, an increase in consolidation stress resulted in a decrease in the void ratio (e) and in the coefficient of volume change (mv), alongside an increase in the coefficient of consolidation (cv). The increased CaCl2 concentration yielded a dropped void ratio, and a nonlinear decreased compression index (Cc) and rebound index (Cs), respectively, from 0.18 to 0.13 and from 0.022 to 0.010, and a nonlinear increase cv. A threshold CaCl2 concentration of 100 mM was observed at the inflection points of the Cc, Cs, and cv. In contrast, the mv was insensitive to the CaCl2 solutions. The deterioration in e, Cc, and Cs and the increase in cv were the result of a compressed diffuse double layer of the bentonite by the CaCl2 solution, which thus exerted certain negative effects on the consolidation behaviors of the SHMP-20CaB backfill.
Hybrid composites combining natural and synthetic fibers offer a pathway to sustainable structural materials, yet their performance is often limited by weak interfacial bonding and mechanical mismatches between constituents. Here, we address these challenges in bamboo/glass fiber hybrid epoxy composites through a sequential alkali and silane surface modification strategy. Alkali treatment removes amorphous lignin and hemicellulose, creating a roughened, cellulose-rich surface; subsequent grafting with (3-aminopropyl) triethoxysilane introduces an amino-functionalized interphase that covalently bonds with the epoxy matrix. This combined treatment increases the tensile strength of bamboo fibers by 51.2% and the interfacial shear strength by 136.6%, reaching values comparable to those of commercial glass fibers. The resulting hybrid composite exhibits a tensile strength of 485 MPa and a flexural modulus of 30.2 GPa, corresponding to improvements of 39.4% and 98.3%, respectively, over the unmodified hybrid system. Dynamic mechanical analysis further confirms an enhanced storage modulus across a wide temperature range. This work demonstrates that rational interfacial design via sequential functionalization offers a viable route to high-performance, lightweight, and structurally stable bamboo/glass fiber hybrid composites for sustainable engineering applications, such as reusable concrete formwork.