On-resonance Rydberg atom–based radio-frequency- (rf) electric-field sensing methods remain limited by the narrow frequency-signal detection bands available from resonant transitions. An additional rf tuner field can be used to dress or shift a target Rydberg state to return a detuned signal field to resonance and thus dramatically extend the frequency range available for resonant sensing. Here we investigate three distinct tuning-level schemes based on adjacent Rydberg transitions, which are shown to have distinct characteristics and can be controlled with the frequency or the strength of the tuning field. We further show that a two-photon Raman peak can be used as an effective tuning feature separate from conventional Autler-Townes splitting. We compare our tuning schemes with ac Stark effect–based broadband rf-field sensing and show that although the sensitivity is diminished with tuning away from a resonant state, it nevertheless can be used in configurations where there is a low density of Rydberg states, which would result in a weak ac Stark effect.

We propose a novel type of Rydberg dimer, consisting of a Rydberg-state atom bound to a distant positive ion. The molecule is formed through long-range electric-multipole interaction between the Rydberg atom and the pointlike ion. We present potential energy curves (PECs) that are asymptotically connected with Rydberg $nP$ or $nD$ states of rubidium or cesium. The PECs exhibit deep, long-range wells which support many vibrational states of Rydberg-atom-ion molecules (RAIMs). We consider photoassociation of RAIMs in both the weak and the strong optical-coupling regimes between initial and Rydberg states of the neutral atom. Experimental considerations for the realization of RAIMs are discussed.

We investigate the effects of spatially non-uniform radio-frequency electric (E) field amplitudes on the spectral line shapes of electromagnetically induced transparency (EIT) signals in Rydberg atomic systems used in electrometry (i.e., the metrology of E-field strengths). Spatially non-uniform fields distort the EIT spectra from that of an ideal case, and understanding this distortion is important in the development of Rydberg atom-based sensors, as these distortions can limit accuracy and sensitivity. To characterize this distortion, we present a model that approximates the atom vapor as multi-layered media and then uses Beer’s law to combine the absorption through its many discrete thin segments. We present a set of expected line distortions caused by various RF electric-field distributions found in practice. This provides an intuitive diagnostic tool for experiments. We compare this model to measured experimental atomic spectra in both two-photon and three-photon excitation schemes in the presence of non-uniform radio-frequency fields. We show that we can accurately model and reproduce the EIT lineshape distortion observed in these experimental data.

We demonstrate resonant detection of rf electric fields from 240 to 900 MHz (very high frequency to ultrahigh frequency) using electromagnetically induced transparency to measure orbital angular momentum $L=3\to L^{\prime }=4$ Rydberg transitions. These Rydberg states are accessible with three-photon infrared optical excitation. By resonantly detecting rf in the electrically small regime, these states enable a new class of atomic receivers. We find good agreement between measured spectra and predictions of quantum defect theory for principal quantum numbers $n=45$ to 70. Using a superhetrodyne detection setup, we measure the noise floor at $n=50$ to be $13\mu \mathrm{V}/\left(\mathrm{m}\sqrt{\mathrm{Hz}}\right)$. Additionally, we utilize data and a numerical model incorporating a five-level master equation solution to estimate the fundamental sensitivity limits of our system.

We present and characterize a Rb atomic vapor cell with silicon-ring electrodes embedded between borosilicate glass tubes. The ring electrodes can be externally connectorized for application of electric fields to the inside of the cell. An atom-based, all-optical, laser-spectroscopic field-sensing method is employed to measure electric fields in the cell. Here, the Stark effect of electric-field-sensitive rubidium Rydberg atoms is exploited to measure dc electric fields in the cell of approximately $5$ V/cm, with a relative uncertainty of 10%. Measurement results are compared with dc field calculations, allowing us to quantify electric field attenuation due to free surface charges inside the cell. We further measure the propagation of microwave fields into the cell, using Autler-Townes splitting of Rydberg levels as a field probe. Results are obtained for a range of microwave powers and polarization angles relative to the cell’s ring electrodes. We compare the results with microwave-field calculations.

We study the expansion of a cold, non-neutral ion plasma into the vacuum. The plasma is initialized by photoionization of cold rubidium atoms in a magneto-optical trap by an ultraviolet laser pulse. We employ time-delayed plasma extraction and imaging onto a position- and time-sensitive microchannel plate detector to analyze the plasma. We report on the formation and persistence of plasma shock shells, pair correlations in the plasma, and external-field-induced plasma focusing effects. We also develop trajectory and fluid descriptions to model the data and to gain further insight. The simulations verify the formation of shock shells and correlations, and allow us to model time- and position-dependent density, temperature, and Coulomb coupling parameter, $\mathrm{\Gamma }(\mathbf{r},t)$. The analysis also shows that the experimental plasma is strongly coupled and elucidates its expansion dynamics.