Abundant biomass is a potential energy source. However, it possesses several challenges when considered for energy applications. Torrefaction, a thermal pretreatment process can improve the properties of biomass as energy source. This study focused on comparing effect of torrefaction operating parameters on agricultural and wood wastes properties as fuel. The physiochemical properties, composition, moisture-biomass interaction and ash melting behavior were determined. The result show that higher torrefaction temperature and longer residence time increased lignin content, reduced hemicellulose and cellulose content. The moisture uptake of torrefied biomass was reduced in the range 2.47–9.94% compared with raw biomass depending on torrefaction temperature that indicate torrefied biomass was more hydrophobic than raw biomass. The moisture adsorption isotherm curve shows type II isotherm based on the Brunauer-Emmett-Teller’s (BET) classification and was best described by the Oswin model. In addition, torrefaction treatment showed significant influence on the melting behavior of the biomass ash. Especially for agricultural wastes, the fouling tendency shifted from serious range to low range with torrefaction treatment. Torrefaction showed promise for improving fuel characteristics of the studied biomass.