In sealing, sliding, and power transmission operations, surface quality and contact tolerances have high impacts on material system efficiency. Although the boriding process improves the wear resistance of metallic surfaces, it increases surface roughness, affecting the tribological efficiency of material systems. This study presents the tribological results of AISI 4140 boriding surfaces tested using a dehydrated paste pack boriding method with and without a finishing polish process to reduce the roughness. The duration of the boriding process was 1 h at 1123, 1173, 1223, and 1273 K using boron paste obtained from a commercial source and using a pot-polishing process with Al₂O₃ with a particle size of 0.5 μm for 25 min. The samples with and without the finishing polish process were structurally characterized using X-ray diffraction, and the boride coating adhesion was determined using Rockwell C indentation. The tribological properties of the boride surface with and without the finishing polish process were determined using a reciprocating sliding test, with a ZrO₂ ball as a counter body. The boride surfaces’ crystalline structure changed with polishing, which revealed the FeB phase and reduced the roughness value. These modifications in the surface characteristics altered the adhesion and tribological performance of the coating, resulting in a more stable tribological performance on the polished boride surfaces, with a reduction in the coefficient of friction (Cof) value from 0.75 ± 0.02 for the tribological test on the 1123 K-P sample to 0.59 ± 0.002 for the 1273 K-P sample surface at 20 N of applied load.

The present work studied the characterization of boriding coatings without and with exposed hydrogen permeation on AISI 8620 through microstructure and mechanical behavior. A dehydrated paste pack process was carried out for the formation of boride coatings on AISI 8620 at 1173, 1223, and 1273K for 6h of exposure time for each temperature. After boronizing, hydrogen was introduced into the borided steels by in situ cathodic charging using an H₂SO₄ acid electrolyte. Specimens borided without and with hydrogen were characterized by scanning electron microscopy with energy dispersive spectroscopy and X-ray diffraction. The experimental techniques of the Vickers microhardness and three-point bending were used. As a result, the hydrogen diffusion on steel AISI 8620 borided shows a significant increase in microhardness. Furthermore, three-point bend tests showed an increased strength on 8620 steel borided. However, the ductility and strength value on 8620 steel borided surfaces presented a drastic reduction due to hydrogen permeation. The results revealed that the borided coatings provided strength and reduced the hydrogen embrittlement index on AISI 8620 borided.

The effect of boron powder on surface AISI W2 steel and growth kinetic of the boride layer is studied. Boron powder mixture was used in the powder pack boriding; this process was carried out in the temperature range from 1173 to 1273 K with exposure times ranging from 2 to 8 h. The presence of boride was confirmed by optical microscopy, X‐ray diffraction, and the distribution of alloy elements in boride layers with energy‐dispersive spectrometry using scanning electron microscopy. A mathematical model of the growth kinetics of the single layer was proposed and boron diffusion coefficient was determined by mass balance equation. The morphology of Fe₂B layer was smooth and boron activation energy in W2 steel was estimated as 187.696 kJ·mol⁻¹. The kinetic model was validated with two experimental conditions, a contour diagram describing the evolution of Fe₂B layer as a function of time and temperature parameters for industrial application.

Hardened AISI 4140 Steel Subjected to Hydrogen - Volume 27 Issue S1

This work studies the mechanical behavior of microalloyed steels (API X60 and API X70) with boride layers using a boriding process and immersion in diesel. First, the microalloyed steels were borided using dehydrated boron paste at a temperature of 1273 K for 6 h, and then the borided microalloyed steels were immersed in diesel for one year. The characterization of the layers on the specimens subjected to diesel used scanning electron microscopy (SEM), energy dispersive spectroscopy, and X-ray diffraction (XRD). The evaluation of the mechanical properties was performed with tensile tests according to ASTM E8, and then the fracture surface was observed by SEM. This work contributes to the understanding of the changes in the mechanical properties of borided microalloyed steel immersed in diesel for possible potential applications in the storage of fuels, oils, hydrogen, and biofuels.

General-purpose polystyrene (GPPS) is widely used in packaging and insulation, although its recyclability poses environmental challenges that require circular economy strategies. The objective of this study was to evaluate the mechanical and tribological behavior of virgin GPPS (100%N), a 50% virgin–50% recycled blend (50N–50R), and 100% recycled GPPS (100%R), processed in Mexico under controlled injection molding conditions. Micro-tensile, flexural, surface roughness, and sliding wear (pin-on-disk) tests were conducted in accordance with ASTM/ANSI standards. The results show that virgin GPPS exhibited the highest strength (micro-tensile: 31.1 MPa; flexural: 87.8 MPa), while the 50N–50R blend maintained comparable tensile strength (27.5 MPa) with greater ductility, making it viable for secondary applications. Recycled GPPS exhibited a significant reduction in strength (micro-tensile: 18.6 MPa; flexural: 41.1 MPa), although with greater deformability. In tribological tests, the coefficients of friction were 0.480 (100%N), 0.128 (50N–50R), and 0.143 (100%R), all with relative errors of less than 4%, confirming statistical validity. Surface roughness analysis showed that the virgin material had the most uniform surface (Ra = 1.0 µm), while the blends exhibited greater variation (Ra ≈ 1.2 µm). In conclusion, although recycled GPPS has limitations compared to virgin material, it retains acceptable mechanical and tribological properties for non-structural applications. These findings support its potential in circular economy strategies in Mexico and provide a framework for countries with similar recycling infrastructure conditions.