The flame retardancy of asphalt binders with layered double hydroxides (LDHs) was investigated using limiting oxygen index (LOI) and cone calorimeter tests. The flame-retardant mechanism of the LDHs was also studied with thermogravimetry and differential scanning calorimetry (TG–DSC), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). The cone calorimeter testing results indicated that 2 wt.% of the LDHs can decease the peak heat and smoke release rate of asphalt binders. Because a low dose of LDHs can be well dispersed in asphalt binder and favor the formation of polyaromatic structures during combustion, the thermal oxidation resistance and compactness of the char layer can be improved. The LOI of asphalt binder can be increased and the heat and smoke release during combustion can be decreased with 25 wt.% LDHs. The decomposition of LDHs can absorb the heat release of the initial two stages of asphalt combustion and reduce the burning rate of asphalt. Due to the loss of loosely bound water in the LDHs during the blending process and the decrease of dispersibility at a high LDH dose, the improvement of thermal stability is limited.
16 September 2025 in Process Safety and Environmental Protection
Low visibility and hot smoke environment under fire conditions can largely hamper the related fire rescue processes. Ultrasound obstacle avoidance technology is then useful for guidance. However, the biggest challenge of adopting ultrasound technology comes from accurate distance measurements under the disturbances of high temperature and soot particle concentration. It is critical to measure the propagation speed under the complicated fire conditions. Therefore, in this study, a baffle calibration method was proposed to improve the accuracy of distance measurement of an obstacle. The method is based on two ultrasound measurement systems, while one is used to calibrate the propagation speed of ultrasound based on the fixed distanced baffle and the other is for the dynamic measurement of obstacle distance based on the calibrated speed. The viability of this method on the guided vehicle was confirmed based on the experiments. From its comparison to those existing methods, such as constant speed and temperature compensation methods, it was known from that the proposed baffle calibration method provides the best prediction. It was obtained that the maximum errors based on the baffle calibration method are 2.75% and 2.62% under the two representative fire scenarios, respectively, which are much lower than those of constant speed (7.81% and 8.4%) and temperature compensation methods (10.4% and 5.12%).
25 September 2023 in Journal of Thermal Analysis and Calorimetry
The thermal protection performance of fire suit is vital to the safety of firefighters. Using certain physical properties of fabrics to evaluate their thermal protection performance speeds up the process. This work aims to develop a TPP value prediction model that can be easily applied. Five properties of three types of Aramid 1414 made of the same material were tested, and the relationships between the physical properties of Aramid 1414 and its thermal protection performance (TPP value) were investigated. The results showed that the TPP value of the fabric had a positive correlation with grammage and air gap, and a negative correlation with the underfill factor. A stepwise regression analysis was used to solve the collinearity issue between the independent variables. Finally, a model for predicting TPP value by air gap and underfill factor was developed. The method adopted in this work reduced the number of independent variables in the prediction model, which is conducive to the application of the model.
22 August 2024 in Journal of Thermal Analysis and Calorimetry