The flame retardancy of asphalt binders with layered double hydroxides (LDHs) was investigated using limiting oxygen index (LOI) and cone calorimeter tests. The flame-retardant mechanism of the LDHs was also studied with thermogravimetry and differential scanning calorimetry (TG–DSC), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). The cone calorimeter testing results indicated that 2 wt.% of the LDHs can decease the peak heat and smoke release rate of asphalt binders. Because a low dose of LDHs can be well dispersed in asphalt binder and favor the formation of polyaromatic structures during combustion, the thermal oxidation resistance and compactness of the char layer can be improved. The LOI of asphalt binder can be increased and the heat and smoke release during combustion can be decreased with 25 wt.% LDHs. The decomposition of LDHs can absorb the heat release of the initial two stages of asphalt combustion and reduce the burning rate of asphalt. Due to the loss of loosely bound water in the LDHs during the blending process and the decrease of dispersibility at a high LDH dose, the improvement of thermal stability is limited.

In this study, ultrasonic pulse velocity (UPV) and ultrasonic shear-wave tomography are combined to measure the residual compressive strength (RCS) of small-scale lining concrete blocks and to detect inner defects in the lining structure. The characteristics of and variations in the RCS of test blocks after being exposed to elevated temperatures (200–800 °C) and constant heating times (2 h, 3 h, and 4 h) were studied. At 800 °C, the RCS values reduced by 64.4%, 69.2%, and 74.6% at heating times of 2 h, 3 h, and 4 h. Scanning electron microscopy (SEM) was used for the micro-phase analysis of the samples that had been exposed to high temperatures. The heating time and RCS as well as the SEM micro-structure relationship were compared. Finally, a tunnel lining slab sample was designed to simulate the post-fire damage inside the blocks. Additionally, shear-wave tomography with 32 probes was able to detect the ϕ10 mm void defects at a depth of 200 mm.

In this study, cone calorimeter and thermogravimetric analyses were used to simulate the asphalt combustion process under the conditions of fire radiation and programmed temperature increase. The gaseous compositions and release rules were analyzed by infrared spectroscopy to investigate the influence of hydrated lime on the smoke suppression mechanism in the asphalt combustion process. The experimental results show that hydrated lime can promote the asphalt mastic surface to form a barrier layer during the combustion process. This barrier layer can reduce the burning intensity of asphalt. Although the compositions of gaseous products do not change much, the rates of CO production and smoke release are decreased. In addition, hydrated lime is alkaline and can thus neutralize acidic gases such as SO₂ and reduce the toxicity of gaseous products. With the addition of 40 wt.% hydrated lime, the total smoke release and the CO release rate both decrease by more than 20% relative to the addition of the same amount of limestone fillers and decrease by more than 10% relative to the addition of the same amount of magnesium hydroxide flame retardant.