The majority of industry using high-speed communication systems is shifting towards higher frequencies, namely the terahertz range, to meet demands of more effective data transfer. Due to the rising number of devices working in terahertz range, effective shielding of electromagnetic interference (EMI) is required, and thus the need for novel shielding materials to reduce the electromagnetic pollution. Here, we show a study on optical and electrical properties of a series of ethylene co-butyl acrylate/carbon black (EBA/CB) composites with various CB loading. We investigate the transmittance, reflectance, shielding efficiency, absorption coefficient, refractive index and complex dielectric permittivity of the fabricated composites. Finally, we report a material that exhibits superior shielding efficiency (SE)—80 dB at 0.9 THz (14.44 vol% CB loading, 1 mm thick)—which is one of the highest SE values among non-metallic composite materials reported in the literature thus far. Importantly, 99% of the incoming radiation is absorbed by the material, significantly increasing its applicability. The absorption coefficient (α) reaches ~100 cm⁻¹ for the samples with highest CB loading. The EBA/CB composites can be used as lightweight and flexible shielding packaging materials for electronics, as passive terahertz absorbers or as radiation shields for stealth applications.

Physical and physico-chemical properties of polymer filled with carbon black (CB) particles, namely, the microstructure dependence of these properties, are not only interesting on their own but are particularly important for electronic applications as they can impose limits on the sensitivity of a device. With this purpose, we report on an experimental study of the structural and electrical properties of semi-crystalline ethylene-co-butyl acrylate polymer filled with conductive CB nano-particles. We found that the value of the direct current conductivity exhibits a jump of 12 orders of magnitude over a small change in CB concentration and is due to a percolation-like behavior. To assess the temperature evolution of supercolative samples, we present measurements of the conductivity as function of temperature. Above the glass transition temperature of the polymer, the CB network restricts the motions of the polymer chains. This behavior was ascribed to the change in CB mesostructure in the polymer matrix as probed by scanning electron microscopy and atomic force microscopy as well as to the difference in the thermal expansion between the two phases. In addition to the observed conductivity increase, the effect of adding CB particles in the polymer matrix is to increase the thermal stability as is probed by thermogravimetric analysis tests. The room temperature alternating current conductivity, studied over the frequency range from 100 Hz to 15 MHz, is interpreted as arising mainly from inter-aggregate polarization effects. By considering carefully the CB content of the alternating current conductivity, we found that our experimental data agree well with the Sheng’s model of fluctuation-induced tunnelling of charge carriers over nanometric gaps between adjacent CB aggregates. For studying the filler content dependence of the effective permittivity, several mixing laws and effective medium theories have been used. The observed discrepancies between our experimental data and these theoretical predictions may be occur partly because these analysis contain an inaccurate knowledge of the physicochemical properties of the carbonaceous phase, give a poor description of the interfaces in these complex heterostructures, or both. As part of the present investigation, present results are compared to transport properties of polystyrene-cobutyl acrylate latex and epoxy resin matrices filled with different loadings of multiwalled carbon nanotubes (MWCNT) and over wide temperature and frequency ranges. It is remarkable that the MWCNT’s anisotropy (length-to-diameter ratio close to 100) manifests itself in percolation-like behavior with lower threshold volume fraction and different mesostructure than that evidenced for CB filled samples.