Experiments on the dissociation of a mixed gas hydrate in various combustion methods are performed. The simultaneous influence of two determining parameters (the powder layer thickness and the external air velocity) on the efficiency of dissociation is studied. It has been shown that for the mixed hydrate, the dissociation rate under induction heating is 10–15 times higher than during the burning of a thick layer of powder, when the combustion is realized above the layer surface. The minimum temperature required for the initiation of combustion for different combustion methods was studied. As the height of the sample layer increases, the rate of dissociation decreases. The emissions of NOx and CO for the composite hydrate are higher than for methane hydrate at the same temperature in a muffle furnace. A comparison of harmful emissions during the combustion of gas hydrates with various types of coal fuels is presented. NOx concentration as a result of the combustion of gas hydrates is tens of times lower than when burning coal fuels. Increasing the temperature in the muffle furnace reduces the concentration of combustion products of gas hydrates.
In this paper, the combustion of methane hydrate over a powder layer is experimentally studied using thermal imaging and Particle Tracking Velocimetry (PTV) methods. The experiments are carried out at different velocities of the external laminar air-flow from zero to 0.6 m/s. Usually, simulation of methane hydrate combustion is carried out without taking into account free convection. A standard laminar boundary layer is often considered for simplification, and the temperature measurements are carried out only on the axis of the powder tank. Measurements of the powder temperature field have shown that there is a highly uneven temperature field on the layer surface, and inside the layer the transverse temperature profiles are nonlinear. The maximum temperature always corresponds to the powder near the side-walls, which is more than 10 °C higher than the average volumetric temperature in the layer. Thermal imager measurements have shown the inhomogeneous nature of combustion over the powder surface and the highly variable velocity of methane above the surface layer. The novelty of the research follows from the measurement of the velocity field using the PTV method and the measurement of methane velocity, which show that the nature of velocity at combustion is determined by the gas buoyancy rather than by the forced convection. The maximum gas velocity in the combustion region exceeds 3 m/s, and the excess of the oxidizer over the fuel leads to more than tenfold violation of the stoichiometric ratio. Despite that, the velocity profile in the combustion region is formed mainly due to free convection, it is also necessary to take into account the external flow of the forced gas U0. Even at low velocities U0, the velocity direction lines significantly deviate under the forced air-flow.