The environmental legislation in Ukraine is changing rapidly. These changes are related to the adaptation of Ukrainian laws to the requirements of the European Union. In this regard, the paper considers the unintentional production of Persistent Organic Pollutants (POPs) in the Odessa Industrial-and-Urban Agglomeration (next - Odessa agglomeration) in the context of new regulatory and legal requirements of Ukraine. In many countries around the world, the issue of pollution of environmental components by POPs has a large focus, because POPs pose a global threat to the environment and human health. The work aims to assess the main sources of unintentional production of POPs in the Odessa agglomeration during one year (2017), taking into account the new territorial features of the Odessa agglomeration. For the first time for Odessa agglomeration, the mass of POPs formed by main sources using the newest European methodological approach was calculated, sources of unintentional production of POPs on volumes of these substances were ranked, and their total mass of generation on the territory of Odessa agglomeration was calculated. The number of POPs molecules equivalent to 2,3,7,8-TCDD, which infiltrate into the air basin of the Odessa agglomeration, hence into the organisms of the agglomeration inhabitants, was calculated. The obtained results were compared with the allowable number per capita of the agglomeration, the relevant conclusions were drawn. Priority sources of unintentional production of POPs were identified, which allows taking appropriate preventive measures to reduce the scale of their generation.

Formulation of the problem. Effective mechanism of wastewater treatment (WT) are important components of reducing anthropogenic load on the environment. One of the most widespread mechanisms of urban wastewater treatment is the biological treatment on a Biological Wastewater Treatment Plant (BWTP). However, increasing the nomenclature of pollutants concentrated in urban wastewater seriously affects the effectiveness of WT on BWTPs, which are not intended for such a wide spectrum of specific pollutants such as, in particular, Persistent Organic Pollutants (POPs). The control of their intake into the environment must be regulated according to the Stockholm convention. The goal of the research is the evaluation of the intake of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) into the environment from the wastewater of Odesa Industrial-and-Urban Agglomeration (IUA) and determining the volumes of their accumulation in the sea environment. Purpose. The assessment of the amount of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/F) entering the environment with the wastewater from Odesa IUA and determining the amount of their accumulation in the sea environment. Methods. In our research, all available official methods of calculation of the unintentional formation of POPs were reviewed, as a result – the main and most complete methods were selected: «UNEP (2013). Toolkit for Identification and Quantification of Releases of Dioxins, Furans and Other Unintentional POPs» and «EMEP/EEA air pollutant emission inventory guidebook. Technical guidance to prepare national emission inventories, 2019». For evaluation of PCDD/F accumulation in the sea environment an improved by authors methodology for calculation of PCDD/F accumulation with their cumulative effect and half life taken into account was used. Results. The work provides justification for the necessity of use of calculation methodologies for determing the intake of PCDD/F to the sea environment adjacent to Odesa IUA; annual massed of PCDD/F entering the sea environment as part of treated, insufficiently treated and untreated wastewater are calculated; massed of PCDD/F that accumulate in waste activated sludge (WAS) on BWTP are calculated; volumes and specifics of PCDD/F accumulation in the sea basin, where the wastewater of Odesa IUA is being discharged to are determined using the improved methodology that enables taking into account the cumulative effect and half life period of these substances; mass and concentration of PCDD/F, immobilized in WAS, are determined, the excess level of concentration of PCDD/F in WAS compared to the maximum permissible concentration is determined. The total accumulation of PCDD/F in the sea environment over 2007-2017 period is determined. Conclusions. It was established that the use of calculation methodologies for evaluating PCDD/F volumes in the water environment is the only and necessary condition for satisfying the requirements of the Stockholm convention due to the impossibility of performing a regular instrumental monitoring of PCDD/F intake into the water environment. The use of suggested by us improved methodology for calculation of PCDD/F accumulation with their cumulative effect and half-life period taken into account allows for calculation of PCDD/F masses that were formed throughout the year under consideration, taking into account the PCDD/F masses that were formed during previous years as well.

Persistent organic pollutants represent a serious global threat to human health and the environment. They have certain properties: resistance to decomposition, bioaccumulation, extreme toxicity, even at ultra-low concentrations, ability to transboundary transfer and deposition. Unfortunately, there is no separate normative and legislative base regulating production of persistent organic pollutants in Ukraine. All norms and rules regulating such pollutants formation are included in a large number of various legislative acts and this does not allow systematization and specification of the actions associated with treatment of POPs. The purpose of this work is to evaluate the main sources of unintentional formation of persistent organic pollutants (using Odessa as an example). As part of the study it was established that the main sources of unintentional formation of POPs in Odessa are: combustion of organic fuels by stationary and mobile sources; production of building materials; open landfills of solid household waste; smoking of meat and fish products; functioning of crematoria; tobacco smoking; functioning of the city sewage system. The analysis of the legislative base of Ukraine is carried out which resulted in making a conclusion that there is no separate normative and legislative base regulating production of persistent organic pollutants in Ukraine. For the first time the list of the main sources of unintentional formation of these pollutants was established for Odessa with estimation, using the most advanced European methods, of the mass of persistent organic pollutants formed from each type of above-stated production facilities, and estimation of the total mass of their generation over the territory of Odessa. Since different techniques give results in different units of measurement, a transition to one unit of measurement was performed. Based on the concept of maximum permissible concentration (MPC), the permissible number of molecules of POPs equivalent to 2,3,7,8- tetrachlorodibenzodioxin (TCDD) which can enter the body of one person through respiratory organs was calculated. A comparison with the number of molecules of 2,3,7,8-TCDD entering the atmosphere in a permissible quantity per 1 citizen of was carried out and corresponding conclusions based on calculations of unintentional formation of POPs in Odessa during one year were made. Also, based on the obtained results, priority sources of unintentional production of persistent organic pollutants were established which allows correct and timely implementation of appropriate measures to reduce formation of these polluting substances.

One of the main environmental polluters, especially in large cities of Ukraine, is road transport. In particular, road transport is one of the main sources of persistent organic pollutants in the environment. Therefore, monitoring of air pollution by road transport is one of the most relevant questions in Ukraine, especially considering its intentions to join the European Union. Analysis of the regulatory and legislative frameworks of Ukraine shows that, unfortunately, today, there are no regulatory documents that motivate to reduce the load of mobile sources, including road transport, on the environment. Moreover, even though the only methodology for calculating pollutant emissions from mobile sources expired in 2015, no new methodology has been developed yet. This paper calculates the masses of pollutants formed during the combustion of gasoline and diesel fuel, and proves the necessity to take into consideration persistent organic pollutants when assessing the toxicity of exhaust fumes, considering their cumulative effect and half-life. The calculation was performed according to European and national (Ukrainian) methodologies, which are supplemented by the calculation of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) formation. Using the relative hazard factor, the relative masses of these substances are calculated, the obtained masses of all components of the exhaust fumes are ranked, the contribution of each component to the toxicity of emissions is revealed. Using emission factors, the specific emissions of these persistent organic pollutants during the combustion of diesel fuel, gasoline, liquefied and compressed gases are calculated. By the results, the types of organic fuels with the highest priority for use by mobile sources are identified.

In today's environment, entropy management of logistics processes in agribusiness is becoming increasingly important due to the need for continuous development and changes in the external environment. Effective logistics management is critical for maintaining the sustainable development and competitiveness of agribusiness. This paper analyzes the role of stevedoring companies, which play a key role in ensuring the reliability and sustainability of supply chains. The paper also considers aspects related to the regulatory framework and the need to improve it to increase the flexibility and adaptability of stevedoring companies in crisis situations. The study was conducted using a systematic approach, which includes an analysis of economic and political conditions, as well as specific aspects of logistics processes in the agribusiness of Ukraine. The article focuses on the management of entropy processes and their impact on the efficiency of logistics operations. It highlights that the proper organization of logistics processes helps to minimize losses and increase the efficiency of supply, which is key for agribusiness in the context of constant development and change. It is shown that stevedoring companies, due to their ability to adapt to changes, have a significant impact on the efficiency of logistics operations and the economic performance of agribusiness. The study found that effective management of entropy processes is crucial for supporting the sustainable development of agribusiness in Ukraine. It emphasizes the need to harmonize Ukrainian legislation with international standards to improve the business environment and attract foreign investors. Thus, the study emphasizes the importance of entropy support for logistics processes in agribusiness and the role of stevedoring companies in ensuring the sustainability and competitiveness of this sector in the context of constant change and development.

The volume of waste left from war-related destruction amounts to 10-12 million tons per year. Such volume is comparable to the annual volume of municipal solid waste generated in Ukraine. This situation led to formation of unauthorized landfills and complicated the existing problem of industrial, consumer, construction and demolition waste management. Consequently, the issue of destruction waste management became a pressing environmental and socio-economic problem. The objective of this research is to assess the characteristics of destruction waste management in the regions of Ukraine. Destruction waste is generated during construction of new buildings and public structures, as well as during renovation or demolition of existing buildings and structures; including general-use facilities. It is estimated that, before the war, nearly 7 million tons of construction and demolition waste was generated annually, with more than 50% being transported to municipal solid waste landfills. Specialized landfills for its disposal were virtually non-existent in the regions of Ukraine, so this waste, despite its resource value, was taken to municipal solid waste landfills or unauthorized dumps. Some components of construction and demolition waste are toxic. Destruction waste includes parts (fragments) of damaged (destroyed) objects, as well as materials and items that were inside or next to such objects at the time of damage (destruction) and/or during disassembly activities, including those that fully or partially lost their consumer properties and cannot be reused at the place of their origin or discovery. Destruction waste pollutes the environment, so one of the ways to reduce environmental risks is to develop an effective waste management system to stop chaotic processes during disassembly activities. Destruction waste differs from construction and demolition waste by the presence of accompanying hazardous components, complicating the development of a waste management system. The main components of destruction waste should be used as secondary raw materials for construction, production of building materials and other purposes. Provided that appropriate physical-geographic, engineering-geological, hydrogeological, technical, and socio-economic conditions are available, it is advisable to create temporary waste storage sites, with their subsequent use as secondary raw materials in the post-war period for restoration of civil, industrial, and transport infrastructure in the regions of Ukraine.