This review covers the latest developments in continuous-variable quantum-state tomography of optical fields and photons, placing a special emphasis on its practical aspects and applications in quantum-information technology. Optical homodyne tomography is reviewed as a method of reconstructing the state of light in a given optical mode. A range of relevant practical topics is discussed, such as state-reconstruction algorithms (with emphasis on the maximum-likelihood technique), the technology of time-domain homodyne detection, mode-matching issues, and engineering of complex quantum states of light. The paper also surveys quantum-state tomography for the transverse spatial state (spatial mode) of the field in the special case of fields containing precisely one photon.

Conventional spectroscopy uses classical light to detect matter properties through the variation of its response with frequencies or time delays. Quantum light opens up new avenues for spectroscopy by utilizing parameters of the quantum state of light as novel control knobs and through the variation of photon statistics by coupling to matter. This Roadmap article focuses on using quantum light as a powerful sensing and spectroscopic tool to reveal novel information about complex molecules that is not accessible by classical light. It aims at bridging the quantum optics and spectroscopy communities which normally have opposite goals: manipulating complex light states with simple matter e.g. qubits versus studying complex molecules with simple classical light, respectively. Articles cover advances in the generation and manipulation of state-of-the-art quantum light sources along with applications to sensing, spectroscopy, imaging and interferometry.

We review the concepts of temporal modes (TMs) in quantum optics, highlighting Roy Glauber’s crucial and historic contributions to their development, and their growing importance in quantum information science. TMs are orthogonal sets of wave packets that can be used to represent a multimode light field. They are temporal counterparts to transverse spatial modes of light and play analogous roles—decomposing multimode light into the most natural basis for isolating statistically independent degrees of freedom. We discuss how TMs were developed to describe compactly various processes: superfluorescence, stimulated Raman scattering, spontaneous parametric down conversion, and spontaneous four-wave mixing. TMs can be manipulated, converted, demultiplexed, and detected using nonlinear optical processes such as three-wave mixing and quantum optical memories. As such, they play an increasingly important role in constructing quantum information networks.

Two-photon absorption (TPA) and other nonlinear interactions of molecules with time–frequency-entangled photon pairs have been predicted to display a variety of fascinating effects. Therefore, their potential use in practical quantum-enhanced molecular spectroscopy requires close examination. This Tutorial presents a detailed theoretical study of one- and two-photon absorption by molecules, focusing on how to treat the quantum nature of light. We review some basic quantum optics theory and then we review the density-matrix (Liouville) derivation of molecular optical response, emphasizing how to incorporate quantum states of light into the treatment. For illustration, we treat in detail the TPA of photon pairs created by spontaneous parametric down conversion, with an emphasis on how quantum light TPA differs from that with classical light. In particular, we treat the question of how much enhancement of the TPA rate can be achieved using entangled states. This Tutorial includes a review of known theoretical methods and results as well as some extensions, especially the comparison of TPA processes that occur via far-off-resonant intermediate states only and those that involve off-resonant intermediate states by virtue of dephasing processes. A brief discussion of the main challenges facing experimental studies of entangled two-photon absorption is also given.

We derive analytical formulas for the forward emission and side emission spectra of cavity-modified single-photon sources, as well as the corresponding normal-mode oscillations in the cavity quantum electrodynamics strong-coupling regime. We investigate the effects of pure dephasing, treated in the phase-diffusion model based on a Wiener-Levy process, on the emission spectra and normal-mode oscillations. We also extend our previous calculation of quantum efficiency to include the pure dephasing process. All results are obtained in the Weisskopf-Wigner approximation for an impulse-excited emitter. We find that the spectra are broadened, the depths of the normal-mode oscillations are reduced and the quantum efficiency is decreased in the presence of pure dephasing.