Mn-1,4-BDC@200 was synthesized, with a capacity of 974 mA h g⁻¹after 100 cycles at a rate of 100 mA g⁻¹.

Metal–organic frameworks (MOFs) have advanced many application fields due to their intriguing structure. However, the application of MOFs in lithium-ion batteries (LIBs) is severely hindered by the lack of a detailed insight into the delithiation and lithiation behaviors of MOFs. This study employs soft X-ray spectroscopy and high-resolution solid-state NMR techniques to study the electrochemical process of a seashell-like Co-based MOF. These experiments demonstrate that Li-ions are intercalated to the carboxyl groups and benzene rings of this MOF during cycling, accompanied by the distortion of CoO₆ octahedral sites. Furthermore, the Co-MOF employing this organic-moiety-dominated intercalation/deintercalation mechanism exhibits high initial coulombic efficiency (80.4%) and unprecedented long-term cyclic stability (1021 mA h g⁻¹ at 100 mA g⁻¹ after 200 cycles; 601 mA h g⁻¹ at 500 mA g⁻¹ after 700 cycles; 435 mA h g⁻¹ at 1 A g⁻¹ after 1000 cycles) when evaluated as the anode material in LIBs. To our knowledge, this is the longest cycle life ever reported for a MOF-based lithium ion battery anode.