In this research work, the electrochemical evaluation of a non-ionic gemini surfactant as a green corrosion inhibitor for X100 pipeline steel in CO₂-saturated brine solution was carried out by electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization curves (PPC). The corrosion inhibition performance of the gemini surfactant was studied in static and hydrodynamic conditions at room temperature and 60 °C. Electrochemical measurements showed that the inhibitor’s performance was enhanced with increasing inhibitor concentration and with increasing exposure time at room temperature, reaching the highest inhibition efficiency (η) at 100 ppm. With increasing temperature, the inhibitor efficiency decreased, with similar behavior at all concentrations. The analysis of the cathodic polarization curves at different rotation speeds showed the strong influence of mass transport on the cathodic process in the absence and the presence of the inhibitor. Under hydrodynamic conditions, PPC and EIS results indicated that the best inhibitor performance was with a concentration of 50 ppm, achieving a maximum inhibition efficiency of 91%. The adsorption of the inhibitor molecules on the surface obeyed the Langmuir isotherm, and the type of adsorption was mixed in all the study conditions. Surface characterization by scanning electron microscopy (SEM) revealed the formation of a protective corrosion inhibitor film.

This paper shows the optimal cost design for T-shaped combined footings of reinforced concrete (RC), which are subjected to biaxial bending in each column to determine the steel areas and the thickness of the footings assuming a linear distribution of soil pressure. The methodology used in this paper is as follows: First, the minimum contact surface between the footing and the ground is investigated. The design equations for the combined footing are then used to determine the objective function and its constraints to obtain the lowest cost, taking into account the ACI code requirements. Flowcharts are shown for the lowest cost and the use of Maple 15 software. The current model for design is developed as follows: A footing thickness is proposed, and then it is verified that the thickness complies with the effects produced by moments, bending shears, and punching shears. Furthermore, four numerical examples are presented under the same loads and moments applied to each column, with different conditions applied to obtain the optimal contact surface and then the minimum cost design. The results show that the optimal cost design (lowest cost) is more economical and more accurate than any other model, and there is no direct proportion between the minimum contact surface and lowest cost for the design of T-shaped combined footings. In this way, the minimum cost model shown in this work can be applied to the design of rectangular and T-shaped combined footings using optimization techniques.

This paper presents an optimal model for the design of elliptical isolated footings subjected to biaxial bending under the minimum cost criterion, assuming that the footing rests on elastic soils and that the soil pressure distribution is linear. The methodology is developed in two parts. The first is used to obtain the minimum area, and the second is used to determine the minimum cost. Some authors show the equations for circular and elliptical footings for moments, bending shear, and punching shear. However, they do not present the minimum cost, and the numerical examples are presented only for circular footings and not for elliptical footings. Two numerical problems are given (each problem presents five variants), and the optimal cost design for elliptical isolated footings subjected to biaxial bending are shown. Problem 1: Modifying the moment on the Y axis. Problem 2: Modifying the axial load. In addition, a comparison is made between elliptical footings and circular footings. The results show that the minimum area is smaller for elliptical footings than for circular footings, and the minimum cost appears in elliptical footings when the footing dimensions are governed by the minimum pressure. Therefore, the new model for elliptical footings will be of great help to foundation engineering specialists.

Este trabajo de investigación muestra la contribución de los materiales cementantes suplementarios (MCS) en la disminución del fenómeno de corrosión en el acero embebido en concreto ternarios. Se elaboraron sistemas acero-concreto ternario, constituidos por acero AISI 1018 (AC) embebidos en concretos ternarios con relación agua/cemento de 0.45. Se realizaron sustituciones parciales con respecto a la masa de cemento portland ordinario (CPO) por ceniza de bagazo de caña de azúcar (CBCA) y ceniza volante (CV) en un 10, 20 y 30 %, el valor de estos porcentajes corresponde al 50 % de CBCA y 50 % de CV. Los sistemas fueron evaluados con la técnica electroquímica de resistencia a la polarización (Rp), donde se analizó la densidad de corriente de corrosión (icorr) y la velocidad de corrosión (Vcorr) como indicadores para evaluar el fenómeno de corrosión. El sistema acero-concreto con el 20 % de sustitución (AC-CT20), disminuyó la Vcorr en un 89 % con respecto al sistema de referencia (AC-REF). Este resultado se atribuyó a que el AC se encuentra en estado pasivo, lo que se asoció con la fomación de la película pasiva que se confirmó con el valor de la media de icorr de 0.09 µA/cm2.

This article presents a complete cost-optimized design for rectangular isolated footings (RIFs) under biaxial bending with a partially compressed contact area (PCCA) and an eccentric column, i.e., part of the base is in contact with the soil (generating compression), and the other part is not in contact with the soil (generating neither compression nor tension), and the soil pressure behaves linearly. The proposed model is presented by integration to find the moments in the critical sections, the bending shears in the critical sections and the punching shear acting on the RIF, and these are compared with those that must be resisted according to the standards (ACI 318-19) Some articles show complete designs for RIFs with a fully compressed contact area (FCCA) and an eccentric column, and other articles show only the minimum area (A_min) for RIFs with a PCCA and an eccentric column. The main contributions of this article are as follows: (1) the A_min is determined from the loads and moments, assuming that the loads and moments it resists must be greater than or equal to those acting on the RIF; (2) the minimum cost (C_min) is determined. Three numerical studies are described to demonstrate the advantages of this study over other models. The results indicate that, according to the studies presented in this article, savings of up to 45.99% for A_min and 93.62% for C_min can be achieved using the model proposed in this article (MPA); this occurs when the pressure acting on the foundation does not reach the maximum available soil pressure (p_max). Therefore, this paper could be of great use to engineers dedicated to the construction of foundations.