Despite the availability of various materials for chimney applications, ongoing research seeks alternatives with improved thermal and chemical resistance. Geopolymers are a promising solution, exhibiting exceptional resistance to high temperatures, fire, and aggressive chemicals. This study investigates fly ash-based lightweight geopolymer concretes that incorporate expanded clay aggregate (E.C.A.), perlite (P), and foamed geopolymer aggregate (F.G.A.). The composites were designed to ensure a density below 1200 kg/m3, reducing overall weight while maintaining necessary performance. Aggregate content ranged from 60 to 75 wt.%. Physical (density, thickness, water absorption), mechanical (flexural and compressive strength), and thermal (conductivity, resistance) properties were evaluated. F.G.A. 60 achieved a 76.8% reduction in thermal conductivity (0.1708 vs. 0.7366 W/(m·K)) and a 140.4% increase in thermal resistance (0.1642 vs. 0.0683). The F.G.A./E.C.A./P 60 mixture showed the highest compressive strength (18.069 MPa), reaching 52.7% of the reference concrete’s strength, with a 32.3% lower density (1173.3 vs. 1735.0 kg/m3). Water absorption ranged from 4.9% (REF.) to 7.3% (F.G.A. 60). All samples, except F.G.A. 70 and F.G.A. 75, endured heating up to 800 °C. The F.G.A./E.C.A./P 60 composite demonstrated well-balanced performance: low thermal conductivity (0.2052 W/(m·K)), thermal resistance up to 1000 °C, flexural strength of 4.386 MPa, and compressive strength of 18.069 MPa. The results confirm that well-designed geopolymer lightweight concretes are suitable for chimney and flue pipe linings operating between 500 and 1000 °C and exposed to acidic condensates and aggressive chemicals. This study marks the initial phase of a broader project on geopolymer-based prefabricated chimney systems.
In this research, polylactide was hybrid-reinforced and heat-treated in order to obtain durable structural materials with the use of eco-friendly components. Differential scanning calorimetry (DSC) analysis, tensile tests at various temperatures, Vicat tests, impact tests, and microscopic observations were conducted on the annealed and non-heat-treated specimens. The theoretical and true density, as well as water absorption, were also determined. The simultaneous introduction of chopped carbon and basalt fibers in equal mass fractions of 7.5% and 12.5% resulted in satisfactory increases in stiffness and tensile strength. The reinforcing effect was more efficient for the heat-treated composites, especially at elevated temperatures. Heat treatment significantly increased the degree of crystallinity of the matrix, improving heat resistance and reducing water absorption. It also reduced the stress concentrations in the injection-molded specimens.
Geopolymer concretes, synthesized from industrial by-products such as fly ash through alkaline activation, have attracted considerable attention due to their favorable thermal and microstructural properties. Incorporating phase change materials (PCMs) into geopolymer matrices can improve thermal properties, making them suitable for various sustainable construction applications. The thermal properties of geopolymer concrete depend on the composition and structure of the materials used. Adding PCMs to geopolymer concrete can significantly improve its thermal properties by increasing its heat storage capacity. PCMs absorb and release thermal energy during phase transformations, which can help regulate temperature fluctuations in building materials. This feature is particularly beneficial in regions with extreme temperature fluctuations, where maintaining a stable indoor climate is crucial. Integrating organic PCMs into geopolymer matrices has been shown to improve thermal insulation. Furthermore, the microstructural analysis of geopolymer concrete containing organic PCM indicates that incorporating these materials can lead to a more homogeneous and denser microstructure. Integrating organic PCMs instead of inorganic into geopolymer concrete is a promising route to improve thermal properties and microstructural stability. The combination of geopolymer technology with PCM not only contributes to the sustainable development of building materials but also addresses the challenges of temperature regulation in buildings.
In the context of the growing need to reduce greenhouse gas emissions and to develop sustainable solutions for the construction industry, foamed geopolymers represent a promising alternative to traditional binders and insulation materials. This study investigates the thermal properties of novel low-emission, insulating geopolymer binders made from fly ash with diatomite, chalcedonite, and wood wool aiming to assess their potential for use in thermal insulation systems in energy-efficient buildings. The stability of the foamed geopolymer structure is also assessed. Measurements of thermal conductivity, specific heat, microstructure, density, and compressive strength are presented. The findings indicate that the selected geopolymer formulations exhibit low thermal conductivity, high heat capacity and low density, making them competitive with conventional insulation materials—mainly load-bearing ones such as aerated concrete and wood wool insulation boards. Additionally, incorporating waste-derived materials reduces the production carbon footprint. The best results are represented by the composite incorporating all three additives (diatomite, chalcedonite, and wood wool), which achieved the lowest thermal conductivity (0.10154 W/m·K), relatively low density (415 kg/m3), and high specific heat (1.529 kJ/kg·K).
W artykule omówiono recykling opakowań PET, podkreślając jego znaczenie w gospodarce obiegu zamkniętego. Przedstawiono metody przetwórstwa odzyskanego materiału i jego potencjalne zastosowania w różnych sektorach gospodarki. Wykazano znaczenie zasady 6R w integracji gospodarki i promowaniu zrównoważonego rozwoju.
This study aims to evaluate the influence of glass fibre (GF) type and content on the thermal, mechanical, and morphological properties of polyethylene terephthalate (PET)-based composites containing post-consumer PET flakes, intended for mouldings exposed to cementitious environments (e.g., anchors). Two chemically resistant GFs were compared: alkali-resistant (AR) fibres with soft sizing (SGFs) and electrical-/chemical-resistant (ECR) fibres with hard sizing (HGFs). Composites with fibre contents of 10–60 wt.% were prepared, with detailed analysis focused on 30 to 50 wt.%—the range typical for practical applications. AR fibres experienced greater shortening during processing, and their actual fibre content was lower than the intended value. Differential scanning calorimetry (DSC) revealed enhanced crystallisation kinetics for SGF composites, with higher crystallinity of the injection-moulded samples and elevated crystallisation temperatures (206–208 °C for SGF vs. 196–197 °C for HGF). Thermogravimetric analysis (TGA) indicated that thermal stability was primarily governed by fibre content; both SGF and HGF composites showed improved resistance compared to neat PET. Mechanical tests demonstrated that both fibre types effectively reinforced the matrix: HGF composites exhibited a higher elastic modulus (20.6 GPa for HGF-50 vs. 18.3 GPa for SGF-50), whereas SGF composites exhibited roughly 10–20% higher tensile, flexural, and impact strength, despite slightly lower fibre content. SEM analysis confirmed more uniform fibre distribution and fewer voids in SGF composites. These results highlight the importance of GF selection for PET composites in alkaline environments, taking into account the properties of the sizing film former and balancing trade-offs between mechanical performance, thermal stability, processability, and economic factors.