Soil aquifer treatment (SAT) is a nature-inspired solution for improving the water quality through soil percolation. The biodegradation of organic matter typically occurs in the shallowest soil layer and it depends on the contaminant’s characteristics (water solubility, molecular structure) and specific soil properties (pore size distribution). The present study aims at identifying which grain size fraction of typically used sandy soils in the shallowest layer of SAT systems can provide the optimal conditions for microbiological growth that can be reached by a trade-off between soil moisture as well as nutrients and oxygen supply. For this, soil columns were used at a laboratory scale to determine the relationship between the pore size distribution of four different grain size fractions and biodegradation rates of organic matter from synthetic wastewater. The results obtained from this experimental setup indicate that bacterial colonies reached optimum growth when about 60% of the available pore space was filled with water. For the selected soil, this was achieved by the fraction with grain sizes in the range of 630 µm to 1000 µm, having pore diameters between 87 µm and 320 µm and a mean pore diameter of 230 µm.

Physical models such as surface infiltration experiments in the lab and field are an approach to understand processes in the unsaturated soil zone. In the case of mapping processes influencing the operation of real-world managed aquifer recharge schemes they are helpful tools to determine interactions between processes in the unsaturated soil zone, and site-specific as well as operational parameters. However, the multitude of assumptions and scale-related limitations of downscale investigations often lead to over- or underestimations, rendering their results useless when translated to field-like conditions. Various real-world managed aquifer recharge operational scenarios were simulated in three physical models, a 1D-lab column, a rectangular shaped stainless steel 3D-lab infiltration tank and a rectangular shaped 3D-field unit, to understand the impact of the experimental set-up on the assessment of processes and to identify the experimental set-up which is most-suitable to describe these processes. Results indicate that water flow velocity, water saturation and oxygen consumption are often overestimated in 1D-column experiments due to sidewall effects and no existing lateral flow. For precise analysis of infiltration processes in general as well as during operation of managed aquifer recharge, 3D experiments are recommended due to their more realistic representation of flow processes.

Trimethylbenzene (TMB) isomers (1,2,3-TMB, 1,2,4-TMB, and 1,3,5-TMB) are often used as conservative tracers in anaerobic, contaminated aquifers for assessing BTEX (benzene, toluene, ethylbenzene, xylenes) biodegradation at field sites. However, uncertainties exist about the behavior of these compounds under anaerobic conditions. For this reason, the influence of various parameters (temperature, residence time) on the biodegradability of TMB isomers was investigated under denitrifying and sulfate-reducing conditions in microcosms and 1D-column experiments. Soil and groundwater contaminated with a cocktail of aromatic hydrocarbons including the TMB isomers, both collected from an industrial site in Berlin, Germany, were used for the laboratory investigations. A continuous and complete biodegradation of 1,3,5-TMB and 1,2,4-TMB under denitrifying conditions was observed independent of realized temperature (10–20 °C) and residence time. Biodegradation of 1,2,3-TMB started after longer lag-phases and was not continuous over the whole experimental period; a strong dependence on temperature and residence time was identified. The biodegradability of all TMB isomers under sulfate-reducing conditions was continuous and complete at higher temperatures (20 °C), whereas no degradation was observed for lower temperatures (10 °C). First-order biodegradation rate constants ranged from 0.05 to 0.21 d⁻¹ for 1,3,5-TMB and 1,2,4-TMB and from 0.01 to 0.11 d⁻¹ for 1,2,3-TMB.

Background: Organic pollutants at contaminated sites are often eliminated naturally by biological degradation. The redox processes responsible can be enhanced by infiltrating electron acceptors such as nitrate or sulfate into the aquifer. However, the addition of oxidative agents can lead to undesired side-effects in the saturated soil zone such as the consumption of nitrate by the oxidation of sulfides contained in the aquifer. Laboratory-scale 1D column experiments in up flow mode were performed to evaluate the potential consumption of nitrate and the related kinetics by the oxidation of sulfides during an enhanced natural attenuation project at a site contaminated with monoaromatic compounds and trimethylbenzene. Water containing nitrate was infiltrated into aquifer soil material containing sulfides. To study side reactions, experiments were conducted with low levels of organic hazardous compounds. Results: The results indicate that sulfide was oxidized with the simultaneous formation of sulfate by nitrate-consuming processes. The degradation rate of sulfide was calculated to be 1.26 mg kg⁻¹ per exchanged pore volume, corresponding to nitrate consumption of 8.5 mg kg⁻¹ in the case of incomplete denitrification and 3.4 mg kg⁻¹ in the case of complete denitrification. Conclusion: The presence of sulfides contained in the soil leads to a nitrate-consuming redox reaction following a linear function in case of sufficient availability of nitrate. This information is helpful for planning ENA projects at contaminated sites to reduce the risk of under- or overdosing the electron acceptor nitrate, which may lead to a lack of nitrate needed to enhance the biodegradation of contaminants in the aquifer or to the deterioration of groundwater quality.

As an alternative to the use of tracers, easy-to-measure soil moisture dynamic parameters (e.g., water content) provide in situ estimates of the infiltration rate reduction state of a soil medium. For instance, managed aquifer recharge operations control the hydraulic state of their infiltration basins by measuring the infiltrated volume under constant head conditions. Instantaneous profile measurement systems can be used to manage the basins by determining the reduction of the infiltration rate over time. This study combines the empirical methods of Libardi, the self-developed water content and root mean square difference-based procedures and the trigger time method, to get a similar reproduction of tracer results from river water spreading basins. The methods based on water content showed a good fitting in comparison to the results obtained with the tracer experiment and represent a promising source for detecting changes in the flow impedance during infiltration events.

Decentralized water management requires innovative technical solutions due to restricted operational and economic resources. In this study, a combined, decentralized infiltration system in the form of closely-spaced sub-systems for precipitation water and treated wastewater has been numerically analyzed. Flow and transport simulation shows that a closely-spaced system, by arranging the infiltration pipes closely in a longitudinal manner, is feasible under the consideration of German national guidelines for both infiltration methods. Precipitation events up to a recurrence interval of five years can be infiltrated alongside with treated wastewater of a one-family house without significant reduction of the wastewaters’ residence time. Scenario analyses highlight that harmless wastewater infiltration remains mainly undisturbed for a broad bandwidth of hydrological, subsurface, and technical conditions.