Water reclamation through the use of soil aquifer treatment (SAT) is a sustainable water management technique with high potential for application in many regions worldwide. However, the fate of contaminants of emerging concern (CECs) during the infiltration of treated wastewater during SAT is still a matter of research. This study investigates the removal capacity of 27 CECs during SAT by means of infiltration experiments into a 6 m soil column. Additionally, the influence of the hydraulic operation of SAT systems on the removal of CECs is investigated by changing the wetting and drying cycle lengths. Sixteen out of 27 CECs are efficiently removed during SAT under various operational modes, e.g., bezafibrate, diclofenac and valsartan. For six substances (4-methylbenzotriazole, amidotrizoic acid, benzotriazole, candesartan, hydrochlorothiazide and sulfamethoxazole), removal increased with longer drying times. Removal of amidotrizoic acid and benzotriazole increased by 85% when the drying cycle was changed from 100 to 444 min. For candesartan and hydrochlorothiazide, removal improved by 35%, and for 4-methylbenzotriazole and sulfamethoxazole, by 57% and 39%, respectively. Thus, enhanced aeration of the vadose soil zone through prolonged drying times can be a suitable technique to increase the removal of CECs during SAT.

Physical models such as surface infiltration experiments in the lab and field are an approach to understand processes in the unsaturated soil zone. In the case of mapping processes influencing the operation of real-world managed aquifer recharge schemes they are helpful tools to determine interactions between processes in the unsaturated soil zone, and site-specific as well as operational parameters. However, the multitude of assumptions and scale-related limitations of downscale investigations often lead to over- or underestimations, rendering their results useless when translated to field-like conditions. Various real-world managed aquifer recharge operational scenarios were simulated in three physical models, a 1D-lab column, a rectangular shaped stainless steel 3D-lab infiltration tank and a rectangular shaped 3D-field unit, to understand the impact of the experimental set-up on the assessment of processes and to identify the experimental set-up which is most-suitable to describe these processes. Results indicate that water flow velocity, water saturation and oxygen consumption are often overestimated in 1D-column experiments due to sidewall effects and no existing lateral flow. For precise analysis of infiltration processes in general as well as during operation of managed aquifer recharge, 3D experiments are recommended due to their more realistic representation of flow processes.

As an alternative to the use of tracers, easy-to-measure soil moisture dynamic parameters (e.g., water content) provide in situ estimates of the infiltration rate reduction state of a soil medium. For instance, managed aquifer recharge operations control the hydraulic state of their infiltration basins by measuring the infiltrated volume under constant head conditions. Instantaneous profile measurement systems can be used to manage the basins by determining the reduction of the infiltration rate over time. This study combines the empirical methods of Libardi, the self-developed water content and root mean square difference-based procedures and the trigger time method, to get a similar reproduction of tracer results from river water spreading basins. The methods based on water content showed a good fitting in comparison to the results obtained with the tracer experiment and represent a promising source for detecting changes in the flow impedance during infiltration events.