Scientific research in the nanomaterials field is constantly evolving, making it possible to develop new materials and above all to find new applications. Therefore, nanoparticles (NPs) are suitable for different applications: nanomedicine, drug delivery, sensors, optoelectronics and food control. This review explores the recent trend in food control of using noble metallic nanoparticles as determination tools. Two major uses of NPs in food control have been found: the determination of contaminants and bioactive compounds. Applications were found for the determination of mycotoxins, pesticides, drug residues, allergens, probable carcinogenic compounds, bacteria, amino acids, gluten and antioxidants. The new developed methods are competitive for their use in food control, demonstrated by their validation and application to real samples.

Purpose: Nowadays, hydroponic cultivation represents a widely used agricultural methodology. The purpose of this paper is to study comparatively on hydroponic substrates. This study is highlighting the best substrate to be involved in hydroponic systems, considering its costs and its sustainability. Design/methodology/approach: Seven substrates were evaluated: rock wool, perlite, vermiculite, peat, coconut fibres, bark and sand. Life cycle assessment (life cycle inventory, life cycle impact assessment (LCIA) and life cycle costing (LCC)) was applied to evaluate the environmental and economic impact. Through the results of the impacts, the carbon footprint of each substrate was calculated. Findings: Perlite is the most impacting substrate, as highlighted by LCIA, followed by rock wool and vermiculite. The most sustainable ones, instead, are sand and bark. Sand has the lower carbon footprint (0.0121 kg CO₂ eq.); instead, bark carbon footprint results in one of the highest (1.1197 kg CO₂ eq.), while in the total impact analysis this substrate seems to be highly sustainable. Also for perlite the two results are in disagreement: it has a high total impact but very low carbon footprint (0.0209 kg CO₂ eq.) compared to the other substrates. From the LCC analysis it appears that peat is the most expensive substrate (€6.67/1,000 cm³), while sand is the cheaper one (€0.26/1,000 cm³). Originality/value: The LCA and carbon footprint methodologies were applied to a growing agriculture practice. This study has highlighted the economic and environmental sustainability of seven substrates examined. This analysis has shown that sand can be the best substrate to be involved in hydroponic systems by considering its costs and its sustainability.

The chemical composition of the inflorescences from four Cannabis sativa L. monoecious cultivars (Ferimon, Uso-31, Felina 32 and Fedora 17), recently introduced in the Lazio Region, was monitored over the season from June to September giving indications on their sensorial, pharmaceutical/nutraceutical proprieties. Both untargeted (NMR) and targeted (GC/MS, UHPLC, HPLC-PDA/FD and spectrophotometry) analyses were carried out to identify and quantify compounds of different classes (sugars, organic acids, amino acids, cannabinoids, terpenoids, phenols, tannins, flavonoids and biogenic amines). All cultivars in each harvesting period showed a THC content below the Italian legal limit, although in general THC content increased over the season. Citric acid, malic acid and glucose showed the highest content in the late flowering period, whereas the content of proline drastically decreased after June in all cultivars. Neophytadiene, nerolidol and chlorogenic acid were quantified only in Felina 32 cultivar, characterized also by a very high content of flavonoids, whereas alloaromadendrene and trans-cinnamic acid were detected only in Uso-31 cultivar. Naringenin and naringin were present only in Fedora 17 and Ferimon cultivars, respectively. Moreover, Ferimon had the highest concentration of biogenic amines, especially in July and August. Cadaverine was present in all cultivars but only in September. These results suggest that the chemical composition of Cannabis sativa L. inflorescences depends on the cultivar and on the harvesting period. Producers can use this information as a guide to obtain inflorescences with peculiar chemical characteristics according to the specific use.

This paper evaluated the environmental impacts of different agronomic practices for a hemp seed crop grown in Mediterranean environment. The following agricultural variables have been considered: seven monoecious hemp varieties(Epsilon68 (E68), Fedora17 (F17), Felina32 (F32), Ferimon (Fe), Futura75 (F75), Santhica27 (S27), Uso31 (U31)), three plant densities (40, 80, and 120 plants m⁻²), and two levels of nitrogen (N) fertilization (50 and 100 kg ha⁻¹ of N). Life cycle assessment (LCA) and carbon footprint (CF) methodologies have been applied to evaluate impacts. In all hemp genotypes, the impacts grew by decreasing both N fertilizer and plants densities. The scenario most impacting was E68/F75/S27 genotypes cultivated with 50 kg ha⁻¹ of N fertilizer and 40 plants m⁻², while the lowest one was Fe with 100 kg ha⁻¹ of N fertilizer and 120 plants m⁻². The highest CF was found for E68/F75/S27 cultivated with 50 kg ha⁻¹ of N fertilizer and 40 plants m⁻² (18.720 kg CO₂ eq). This study highlighted the most environmentally sustainable agronomic practices to support farmer and decision maker in Cannabis sativa L. cultivation for seed production.

Olive oil is one of the most globally recognized high-value products, with 4 million hectares cultivated in the Mediterranean area. The production process involves many stages: farming, extraction, packing, and waste treatment. Each one of these stages should present critical points for the environmental impacts, and for this reason, the entire sector is adopting mitigation strategies to begin to be more sustainable. The mitigation actions’ efficiency should be evaluated through environmental indicators or environmental impact assessment by Life Cycle Assessment (LCA). This review aimed to carry out an overview of recent papers (2011–2021) involving an LCA study in the olive oil supply chain by giving a framework of what is included in LCA studies and highlighting the main contributors to environmental impacts. The main scholarly literature databases have been exploited, highlighting a great increase in publications, especially from the producer countries. The review results reflect the heterogeneity of the production process. However, the use of pesticides, fertilizers, water, and fuel for machinery heavily weigh on the farming stage’s environmental impact. Finally, special focus was given to key elements of LCA studies in the olive oil supply chain, such as functional unit, system boundaries, impact categories, calculation method, and software widely used.

The chemical profile of the female inflorescence extracts from seven Cannabis sativa L. dioecious cultivars (Carmagnola, Fibranova, Eletta Campana, Antal, Tiborszallasi, Kompolti, and Tisza) was monitored at three harvesting stages (4, 14, and 30 September), reaching from the beginning of flowering to end of flowering/beginning of seed formation, using untargeted nuclear magnetic resonance (NMR) and targeted (ultra-high-performance liquid chromatography (UHPLC) and spectrophotometry) analyses. The tetrahydrocannabinol content was always below the legal limits (<0.6%) in all the analyzed samples. The NMR metabolite profile (sugars, organic acids, amino acids, and minor compounds) subjected to principal components analysis (PCA) showed a strong variability according to the harvesting stages: samples harvested in stage I were characterized by a high content of sucrose and myo-inositol, whereas the ones harvested in stage II showed high levels of succinic acid, alanine, valine, isoleucine, phenylalanine, and threonine. Samples harvested in stage III were characterized by high levels of glucose, fructose, choline, trigonelline, malic acid, formic acid, and some amino acids. The ratio between chlorophylls and carotenoids content indicated that all plants grew up exposed to the sun, the Eletta Campana cultivar having the highest pigment amount. Tiborszallasi cultivar showed the highest polyphenol content. The highest antioxidant activity was generally observed in stage II. All these results suggested that the Cannabis sativa L. inflorescences of each analyzed dioecious hemp cultivar presented a peculiar chemical profile affected by the harvesting stage. This information could be useful for producers and industries to harvest inflorescences in the appropriate stage to obtain samples with a peculiar chemical profile suitable for proper applications.