Towards the need for sustainable development, remote sensing (RS) techniques in the Visible-Near Infrared–Shortwave Infrared (VNIR–SWIR, 400–2500 nm) region could assist in a more direct, cost-effective and rapid manner to estimate important indicators for soil monitoring purposes. Soil reflectance spectroscopy has been applied in various domains apart from laboratory conditions, e.g., sensors mounted on satellites, aircrafts and Unmanned Aerial Systems. The aim of this review is to illustrate the research made for soil organic carbon estimation, with the use of RS techniques, reporting the methodology and results of each study. It also aims to provide a comprehensive introduction in soil spectroscopy for those who are less conversant with the subject. In total, 28 journal articles were selected and further analysed. It was observed that prediction accuracy reduces from Unmanned Aerial Systems (UASs) to satellite platforms, though advances in machine learning techniques could further assist in the generation of better calibration models. There are some challenges concerning atmospheric, radiometric and geometric corrections, vegetation cover, soil moisture and roughness that still need to be addressed. The advantages and disadvantages of each approach are highlighted and future considerations are also discussed at the end.

Rapid and cost-effective soil properties estimations are considered imperative for the monitoring and recording of agricultural soil condition for the implementation of site-specific management practices. Conventional laboratory measurements are costly and time-consuming, and, therefore, cannot be considered appropriate for large datasets. This article reviews laboratory and proximal sensing spectroscopy in the visible and near infrared (VNIR)–short wave infrared (SWIR) wavelength region for soil organic carbon and soil organic matter estimation as an alternative to analytical chemistry measurements. The aim of this work is to report the progress made in the last decade on data preprocessing, calibration approaches, and system configurations used for VNIR-SWIR spectroscopy of soil organic carbon and soil organic matter estimation. We present and compare the results of over fifty selective studies and discuss the factors that affect the accuracy of spectroscopic measurements for both laboratory and in situ applications.

Remote sensing and soil spectroscopy applications are valuable techniques for soil property estimation. Soil organic matter (SOM) and calcium carbonate are important factors in soil quality, and although organic matter is well studied, calcium carbonates require more investigation. In this study, we validated the performance of laboratory soil spectroscopy for estimating the aforementioned properties with referenced in situ data. We also examined the performance of imaging spectroscopy sensors, such as the airborne HySpex and the spaceborne PRISMA. For this purpose, we applied four commonly used machine learning algorithms and six preprocessing methods for the evaluation of the best fitting algorithm.. The study took place over crop areas of Amyntaio in Northern Greece, where extensive soil sampling was conducted. This is an area with a very variable mineralogical environment (from lignite mine to mountainous area). The SOM results were very good at the laboratory scale and for both remote sensing sensors with R² = 0.79 for HySpex and R² = 0.76 for PRISMA. Regarding the calcium carbonate estimations, the remote sensing accuracy was R² = 0.82 for HySpex and R² = 0.36 for PRISMA. PRISMA was still in the commissioning phase at the time of the study, and therefore, the acquired image did not cover the whole study area. Accuracies for calcium carbonates may be lower due to the smaller sample size used for the modeling procedure. The results show the potential for using quantitative predictions of SOM and the carbonate content based on soil and imaging spectroscopy at the air and spaceborne scales and for future applications using larger datasets.

Soil properties estimation with the use of reflectance spectroscopy has met major advances over the last decades. Their non-destructive nature and their high accuracy capacity enabled a breakthrough in the efficiency of performing soil analysis against conventional laboratory techniques. As the need for rapid, low cost, and accurate soil properties’ estimations increases, micro electro mechanical systems (MEMS) have been introduced and are becoming applicable for informed decision making in various domains. This work presents the assessment of a MEMS sensor (1750–2150 nm) in estimating clay and soil organic carbon (SOC) contents. The sensor was first tested under various experimental setups (different working distances and light intensities) through its similarity assessment (Spectral Angle Mapper) to the measurements of a spectroradiometer of the full 350–2500 nm range that was used as reference. MEMS performance was evaluated over spectra measured from 102 samples in laboratory conditions. Models’ calibrations were performed using random forest (RF) and partial least squares regression (PLSR). The results provide insights that MEMS could be employed for soil properties estimation, since the RF model demonstrated solid performance over both clay (R² = 0.85) and SOC (R² = 0.80). These findings pave the way for supporting daily agriculture applications and land related policies through the exploration of a wider set of soil properties.