Biochar application has been considered as a rich source of carbon which helps to improve the physico-chemical properties and fertility of the soil. In Pakistan, excessive use of nitrogen fertilizer is considered a serious problem, so it is of vital importance to examine the effect of biochar on soil with varying doses of nitrogen fertilizer. We hypothesized that addition of biochar to an alkaline calcareous soil could improve not only soil quality and crop yield but also nitrogen use efficiency (NUE), reducing the loss of nitrogen (N) in the form of denitrification, ammonia volatilization, and nitrate leaching. A pot experiment was conducted under 2-factorial completely randomized design having three replications to evaluate the NUE in biochar amended calcareous soil. Biochar was applied at the rate of 0%, 1% and 2% (w/w) in pots filled with 17 kg of soil using various levels of N (0%, 50% and 100% of recommended dose) on maize (Zea mays L.). Several soil quality indicators, uptake, and yield of maize were monitored. Biochar application significantly decreased soil pH, increased water-holding capacity, total organic carbon, maize yield, stomatal conductance, and nitrogen uptake in plant. The results of the study indicated that addition of biochar could not only decrease the use of inorganic fertilizers by improving its quality and yield as in our case biochar at the rate of 1% and N at the rate of 50% provided optimum output minimizing the economic cost eventually.

View angle effects present in crop canopy spectra are critical for the retrieval of the crop canopy leaf area index (LAI). In the past, the angular effects on spectral vegetation indices (VIs) for estimating LAI, especially in crops with different plant architectures, have not been carefully assessed. In this study, we assessed the effects of the view zenith angle (VZA) on relationships between the spectral VIs and LAI. We measured the multi-angular hyperspectral reflectance and LAI of two cultivars of winter wheat, erectophile (W411) and planophile (W9507), across different growing seasons. The reflectance of each angle was used to calculate a variety of VIs that have already been published in the literature as well as all possible band combinations of Normalized Difference Spectral Indices (NDSIs). The above indices, along with the raw reflectance of representative bands, were evaluated with measured LAI across the view zenith angle for each cultivar of winter wheat. Data analysis was also supported by the use of the PROSAIL (PROSPECT + SAIL) model to simulate a range of bidirectional reflectance. The study confirmed that the strength of linear relationships between different spectral VIs and LAI did express different angular responses depending on plant type. LAI–VI correlations were generally stronger in erectophile than in planophile wheat types, especially at the zenith angle where the background is expected to be more evident for erectophile type wheat. The band combinations and formulas of the indices also played a role in shaping the angular signatures of the LAI–VI correlations. Overall, off-nadir angles served better than nadir angle and narrow-band indices, especially NDSIs with combinations of a red-edge (700~720 nm) and a green band, were more useful for LAI estimation than broad-band indices for both types of winter wheat. But the optimal angles much differed between two plant types and among various VIs. High significance (R² > 0.9) could be obtained by selecting appropriate VIs and view angles on both the backward and forward scattering direction. These results from the in-situ measurements were also corroborated by the simulation analysis using the PROSAIL model. For the measured datasets, the highest coefficient was obtained by NDSI(536,720) at −35° in the backward (R² = 0.971) and NDSI(571,707) at 55° in the forward scattering direction (R² = 0.984) for the planophile and erectophile varieties, respectively. This work highlights the influence of view geometry and plant architecture. The identification of crop plant type is highly recommended before using remote sensing VIs for the large-scale mapping of vegetation biophysical variables.

The prime objective of biochar production is to contribute to nutrients recycling, reducing waste and converting useful bio-wastes into carbon rich products in the environment. The present study was intended to systematically evaluate the effect of pyrolysis conditions and characteristics of feedstock influencing the generation of biochar. The study revealed the nutritional importance of waste mushroom substrate (WMS) biochar which may elevate soil nutritional status and soil quality. The results showed that the yields and properties of WMS biochar depended principally on the applied temperature where pyrolysis at higher temperatures, that is, 600 °C and 700 °C produced biochar having high ash, P and K contents. Moreover, numerous useful macro and micro nutrients such as Ca, Mg, Fe and Zn were observed to positively correlate with the increase in temperature. The WMS biochar in our study is highly alkaline which can be used to rectify acidic soil pH. Overall our results suggest that WMS biochar being a rich source of nutrients can be the best remedy to maintain and further enhance the soil nutritional status. Thus by interpreting biochar feedstock characteristics and pyrolysis conditions, the regulation of tailored WMS biochar manufacturing and application in soil can be facilitated.

Soil organic carbon (SOC) models were often applied to regions with high heterogeneity, but limited spatially differentiated soil information and simulation unit resolution. This study, carried out in the Tai-Lake region of China, defined the uncertainty derived from application of the DeNitrification-DeComposition (DNDC) biogeochemical model in an area with heterogeneous soil properties and different simulation units. Three different resolution soil attribute databases, a polygonal capture of mapping units at 1∶50,000 (P5), a county-based database of 1∶50,000 (C5) and county-based database of 1∶14,000,000 (C14), were used as inputs for regional DNDC simulation. The P5 and C5 databases were combined with the 1∶50,000 digital soil map, which is the most detailed soil database for the Tai-Lake region. The C14 database was combined with 1∶14,000,000 digital soil map, which is a coarse database and is often used for modeling at a national or regional scale in China. The soil polygons of P5 database and county boundaries of C5 and C14 databases were used as basic simulation units. Results project that from 1982 to 2000, total SOC change in the top layer (0–30 cm) of the 2.3 M ha of paddy soil in the Tai-Lake region was +1.48 Tg C, −3.99 Tg C and −15.38 Tg C based on P5, C5 and C14 databases, respectively. With the total SOC change as modeled with P5 inputs as the baseline, which is the advantages of using detailed, polygon-based soil dataset, the relative deviation of C5 and C14 were 368% and 1126%, respectively. The comparison illustrates that DNDC simulation is strongly influenced by choice of fundamental geographic resolution as well as input soil attribute detail. The results also indicate that improving the framework of DNDC is essential in creating accurate models of the soil carbon cycle.