The utilization of the anodic TiO₂ nanotube layers, with uniform Al₂O₃ coatings of different thicknesses (prepared by atomic layer deposition, ALD), as the new electrode material for lithium-ion batteries (LIBs), is reported herein. Electrodes with very thin Al₂O₃ coatings (∼1 nm) show a superior electrochemical performance for use in LIBs compared to that of the uncoated TiO₂ nanotube layers. A more than 2 times higher areal capacity is received on these coated TiO₂ nanotube layers (∼75 vs 200 μAh/cm²) as well as higher rate capability and coulombic efficiency of the charging and discharging reactions. Reasons for this can be attributed to an increased mechanical stability of the TiO₂ nanotube layers upon Al₂O₃ coating, as well as to an enhanced diffusion of the Li⁺ ions within the coated nanotube layers. In contrast, thicker ALD Al₂O₃ coatings result in a blocking of the electrode surface and therefore an areal capacity decrease.

In this paper, we demonstrate the first attempt of encapsulating a flexible micro battery into a contact lens to implement an eye-tracker. The paper discusses how to scale the battery to power various circuits embedded in the contact lens, such as ASIC, photodiodes, etc., as well as how to combine the battery with external harvested energy sources. The fabricated ring battery has a surface area of 0.75 cm² yielding an areal capacity of 43 µAh·cm⁻² at 20C. Based on simulated 0.35-µm CMOS ASIC power consumption, this value is large enough to allow powering the ASIC for 3 minutes. The functioning of the micro battery is demonstrated by powering an orange LED.

Carbon nanotubes (CNT) are used as anodes for flexible Li-ion micro-batteries. However, one of the major challenges in the growth of flexible micro-batteries with CNT as the anode is their immense capacity loss and a very low initial coulombic efficiency. In this study, we report the use of a facile direct pre-lithiation to suppress high irreversible capacity of the CNT electrodes in the first cycles. Pre-lithiated polymer-coated CNT anodes displayed good rate capabilities, studied up to 30 C and delivered high capacities of 850 mAh g⁻¹ (313 μAh cm⁻²) at 1 C rate over 50 charge-discharge cycles.