The thermal performance of wood–plastic composites (WPCs) with different fiber, different fiber contents, and different lubricants were investigated in this paper. The results show that the thermal degradation temperature, melting temperature, crystallization temperature, crystallinity, and viscosity of WPCs with wood fiber were slightly higher than those of WPCs with floor sanding powder and rice husk. As the wood fiber content increased, the melting temperature and crystallinity of WPCs decreased while the crystallization temperature, viscosity, and pseudoplasticity increased. When the wood fiber content was increased to 60%, the dimensional stability of WPCs tended to be constant, and a higher wood fiber content was not conducive for processing of WPCs. WPCs had a small coefficient of linear thermal expansion at low temperature and demonstrated a good dimensional stability. The presence of lubricant reduced the viscosity and increased the pseudoplasticity of the WPCs, which is advantageous for the dimensional stability of WPCs at low temperature while making it worse for high temperatures.
The advancement in science and technology has led to luffa sponge (LS) being widely used as a natural material in industrial application because of its polyporous structure and light texture. To enhance the utility of LS fibers as the reinforcement of lightweight composite materials, the current study investigates their water absorption, mechanical properties, anatomical characteristics and thermal performance. Hence, moisture regain and tensile properties of LS fiber bundles were measured in accordance with American Society for Testing and Materials (ASTM) standards while their structural characteristics were investigated via microscopic observation. Scanning electron microscopy (SEM) was used to observe the surface morphology and fractured surface of fiber bundles. The test results show that the special structure where the phloem tissues degenerate to cavities had a significant influence on the mechanical properties of LS fiber bundles. Additionally, the transverse sectional area occupied by fibers in a fiber bundle (SF), wall thickness, ratio of wall to lumen of fiber cell, and crystallinity of cellulose had substantial impact on the mechanical properties of LS fiber bundles. Furthermore, the density of fiber bundles of LS ranged within 385.46–468.70 kg/m3, significantly less than that of jute (1360.40 kg/m3) and Arenga engleri (950.20 kg/m3). However, LS fiber bundles demonstrated superior specific modulus than Arenga engleri.
The crack initiation point can be regarded as a sign of composite failure and plays a vital role in the evaluation of fracture toughness. Wood-plastic composites (WPCs) are viscoelastic materials and the evaluation of fracture mechanism and toughness has a great significance in their applications. Therefore, we used the acoustic emission (AE) technique to measure the crack initiation point of the WPCs and evaluate their fracture toughness. The results show that the novel AE-based methods were more effective than the conventional standard methods for characterization of the crack initiation point. Using the relationship of cumulative AE events with time and load, the critical failure load was quickly determined, and then the critical stress intensity factor and fracture toughness were calculated. The fracture toughness of the WPCs increased with an increase in the wood fiber content.
To promote the application of polyamide 6 (PA6) in wood–plastic composites, the negative effects associated with the thermal degradation of plant fibers must be overcome. In this study, waste bamboo fibers were subjected to pyrolysis and ball milling to afford nano bamboo-based biochar (BC), which was subsequently used as reinforcement to prepare PA6/BC nano composites by injection molding. In addition, the processing fluidity, water absorption, mechanical properties, and interface compatibility of PA6/BC composites were discussed. Results revealed that a BC content of less than 30 wt% is beneficial to improve the processing fluidity of the composites. With the increase in the BC content, the density of the PA6/BC composites gradually increased, while the water absorption of the PA6/BC composites gradually decreased, and the maximum decrease was 46%. Compared to that of pure PA6, the mechanical strength of PA6/BC composites was improved by the addition of BC, and the maximum tensile/flexural strength and modulus of PA6/BC composites increased by 41%/72% and 195%/244%, respectively. However, the impact strength decreased by 27%. After immersion treatment, the dimensional stability and mechanical strength of the composites decreased, while toughness improved. At a BC content of less than 40 wt%, BC particles exhibited good dispersibility and wettability in the PA6 matrix, and the rough surface and rich pore structure of BC rendered strong mechanical interlocking effects and good interface compatibility, thereby enhancing the mechanical properties of the composites.
The damage and fracture of fiber reinforced polymer composites are vital constraints in their applications. To understand the mechanism of damage of wood fiber (WF) reinforced high density polyethylene (HDPE) composites, we used waste WF and recycled HDPE (Re-HDPE) as the raw materials and prepared high-filled WF/Re-HDPE composites via extrusion. The damage and fracture mode and failure mechanism of the composites with different WF contents (50%, 60%, and 70%) was studied under a three-point bending test by combining the acoustic emission (AE) technique and scanning electron microscope (SEM) analysis. The results show that AE technology can better assist in understanding the progress of damage and fracture process of WF/Re-HDPE composites, and determine the damage degree, damage accumulation, and damage mode. The damage and fracture process of the composites presents three main stages: the appearance of initial damage, damage accumulation, and destructive damage to fracture. The matrix deformation, fiber breakage, interface delamination, fiber-matrix debonding, fiber pull-out, and matrix cracking were the dominant modes for the damage of high-filled WF/Re-HDPE composites under bending load, and the AE signal changed in different damage stages and damage modes. In addition, the WF content and repeated loading had a significant influence on the composite’s damage and fracture. The 50% and 60% WF/Re-HDPE composites produced irreversible damage when repeated load exceeded 75% of the maximum load, while 25% of the maximum load could cause irreversible damage for 70% WF/Re-HDPE composites. The damage was accumulated owing to repeated loading and the mechanical properties of the composites were seriously affected.
Poly(3-hydroxybutyrate–co–3-hydroxyvalerate) (PHBV) is a biodegradable polymer and has several potential applications. Herein, we have used a rich biomass resource, rice husk, to obtain rice husk nano-SiO2 (RHNS) and prepared RHNS/PHBV composites by using hot-press molding. The results showed that the amorphous nature of spherical nano-SiO2 particles with an average diameter of 40–80 nm was obtained. The tensile strength and flexural strength of the RHNS/PHBV-3 composite reached up to 23.515 and 75.669 MPa, respectively, corresponding to an increase of 33.65% and 15.54% as compared to pure PHBV. The enhanced mechanical properties of the RHNS/PHBV composite can be attributed to the uniform dispersion and strong interfacial bonding of RHNS with the PHBV matrix. In addition, the water absorption rate of the RHNS/PHBV composite increased from 0.26% to 0.35% and the water swelling ratio followed the given order in different directions: thickness > width > length. Furthermore, the initial degradation temperature and residual rate of combustion at 700 °C of the composites increased with higher content of RHNS, which represents the enhanced thermal stability of RHNS/PHBV composites. In summary, RHNS served as an excellent reinforcement and RHNS/PHBV composites have shown promising properties for various potential applications.